Skip to main content
Ch.15 - Chemical Kinetics
Chapter 15, Problem 38a

This reaction is first order in N2O5: N2O5(g) → NO3(g) + NO2(g) The rate constant for the reaction at a certain temperature is 0.053/s. a. Calculate the rate of the reaction when [N2O5] = 0.055 M

Verified step by step guidance
1
Identify the order of the reaction with respect to N<sub>2</sub>O<sub>5</sub>. Since the reaction is first order in N<sub>2</sub>O<sub>5</sub>, the rate law can be expressed as Rate = k[N<sub>2</sub>O<sub>5</sub>].
Substitute the given rate constant (k) into the rate law. The rate constant k is given as 0.053/s.
Substitute the concentration of N<sub>2</sub>O<sub>5</sub> into the rate law. The concentration [N<sub>2</sub>O<sub>5</sub>] is given as 0.055 M.
Calculate the rate of the reaction by multiplying the rate constant by the concentration of N<sub>2</sub>O<sub>5</sub>. Use the formula: Rate = (0.053/s) * (0.055 M).
Express the final rate of the reaction in appropriate units, which in this case would be M/s (molarity per second).

Verified Solution

Video duration:
1m
This video solution was recommended by our tutors as helpful for the problem above.
Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

First-Order Reactions

A first-order reaction is one where the rate of reaction is directly proportional to the concentration of one reactant. In this case, the rate can be expressed as rate = k[N2O5], where k is the rate constant. This means that if the concentration of N2O5 changes, the rate of the reaction will change linearly with it.
Recommended video:
Guided course
02:29
First-Order Reactions

Rate Constant (k)

The rate constant (k) is a proportionality factor that relates the rate of a reaction to the concentration of reactants. It is specific to a given reaction at a particular temperature. In this question, the rate constant is given as 0.053/s, which indicates how quickly the reaction proceeds under the specified conditions.
Recommended video:
Guided course
01:14
Equilibrium Constant K

Concentration and Rate Calculation

To calculate the rate of a reaction, you multiply the rate constant (k) by the concentration of the reactant. For the given reaction, with [N2O5] at 0.055 M, the rate can be calculated using the formula rate = k[N2O5]. This allows us to determine how fast the reaction is occurring at that specific concentration.
Recommended video:
Guided course
02:28
Stoichiometric Rate Calculations
Related Practice
Textbook Question

This graph shows a plot of the rate of a reaction versus the concentration of the reactant.

b. Make a rough sketch of a plot of [A] versus time

844
views
Textbook Question

This graph shows a plot of the rate of a reaction versus the concentration of the reactant.

c. Write a rate law for the reaction including the value of k.

492
views
Textbook Question

What are the units of k for each type of reaction?

a. first-order reaction

b. second-order reaction

c. zero-order reaction

1049
views
Textbook Question

This reaction is first order in N2O5: N2O5(g) → NO3(g) + NO2(g) The rate constant for the reaction at a certain temperature is 0.053/s. b. What would the rate of the reaction be at the concentration indicated in part a if the reaction were second order? Zero order? (Assume the same numerical value for the rate constant with the appropriate units.)

2747
views
1
rank
Textbook Question

A reaction in which A, B, and C react to form products is first order in A, second order in B, and zero order in C. b. What is the overall order of the reaction?

422
views
Textbook Question

A reaction in which A, B, and C react to form products is first order in A, second order in B, and zero order in C c. By what factor does the reaction rate change if [A] is doubled (and the other reactant concentrations are held constant)? d. By what factor does the reaction rate change if [B] is doubled (and the other reactant concentrations are held constant)? e. By what factor does the reaction rate change if [C] is doubled? f. By what factor does the reaction rate change if the concentrations of all three reactants are doubled?

858
views