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Ch.15 - Chemical Kinetics

Chapter 15, Problem 48a

Indicate the order of reaction consistent with each observation. a. The half-life of the reaction gets shorter as the initial concentration is increased.

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Hey everyone in this example, we need to determine the order of a reaction. For reaction with a half life that decreases as the initial concentration increases. So what we should recall is our half life calculation for a second order kinetic reaction. And we should recall that that formula is equal to one divided by the rate constant K. Multiplied by our initial concentration of our reactant. And so we would see that because half life is in the numerator and our initial concentration of our reactant is in the denominator. We would say that half life has an inverse relationship with our initial concentration. And so we would say that therefore if we increase our half life we would therefore decrease our initial concentration of our reactant. And likewise, if we decrease half life we would increase our initial concentration of our reactant. And so according to the prompt, we would confirm that the correct answer choice is going to be choice C which states that the reaction is going to be second order. Because we have outlined the formula for calculating the half life of a second order reaction. And we saw the inverse relationship between half life and our initial concentration of our reactant. So if you have any questions, just leave them down below. Otherwise I will see everyone in the next practice video
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Textbook Question

Indicate the order of reaction consistent with each observation c. The half-life of the reaction gets longer as the initial concentration is increased.

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The tabulated data show the concentration of AB versus time for this reaction: AB( g)¡A( g) + B( g) Time (s) [AB] (M) 0 0.950 50 0.459 100 0.302 150 0.225 200 0.180 250 0.149 300 0.128 350 0.112 400 0.0994 450 0.0894 500 0.0812 Determine the order of the reaction and the value of the rate constant. Predict the concentration of AB at 25 s.

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Textbook Question

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