Classify each of the following as a component of a silicate ceramic, an oxide ceramic, or a nonoxide ceramic. c. MoSi2
Ch.13 - Solids & Modern Materials
Chapter 13, Problem 61
How many molecular orbitals are present in the conduction band of a lithium crystal with a mass of 11.2 g?
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Molecular Orbitals
Molecular orbitals are formed by the linear combination of atomic orbitals when atoms bond together. In a solid, these orbitals can extend over many atoms, leading to the formation of bands, such as the conduction band, which allows for the movement of electrons. Understanding how these orbitals combine is crucial for analyzing the electronic properties of materials.
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Conduction Band
The conduction band is a range of energy levels in a solid where electrons can move freely, contributing to electrical conductivity. Electrons in this band are not bound to any particular atom, allowing them to conduct electricity. The number of molecular orbitals in the conduction band is related to the number of atoms in the crystal and their respective atomic orbitals.
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Lithium Crystal Structure
Lithium, being a metal, has a body-centered cubic (BCC) crystal structure, which influences its electronic properties. The arrangement of lithium atoms in this structure determines how many atomic orbitals combine to form molecular orbitals in the conduction band. The mass of the lithium crystal can help determine the number of atoms present, which is essential for calculating the total number of molecular orbitals.
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Related Practice
Textbook Question
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Textbook Question
Which solid would you expect to have little or no band gap? a. Zn(s) b. Si(s) c. As(s)
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Textbook Question
Which solid would you expect to have the largest band gap? a. As(s) b. Sb(s) c. Bi(s)
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Textbook Question
A substance has a band gap of 6.9 eV at 273 K. Is this substance best classified as an insulator, a semiconductor, or a metal?
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Textbook Question
Indicate if each solid forms an n-type or a p-type semiconductor.
a. silicon doped with gallium
b. germanium doped with antimony
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Textbook Question
Does a photon of red light with a frequency of 4.29⨉1014 Hz have sufficient energy to promote an electron from the valence band to the conduction band in a sample of silicon (the band gap in silicon is 1.11 eV)?
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