Plonium crystallizes with a simple cubic structure. It has a density of 9.3 g/cm3, a radius of 167 pm, and a molar mass of 209 g/mol. Use these data to calculate Avogadro's number (the number of atoms in one mole).
Ch.13 - Solids & Modern Materials
Chapter 13, Problem 29b
Determine the number of atoms per unit cell for each metal.
(b) Tungsten
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Unit Cell
A unit cell is the smallest repeating unit in a crystal lattice that reflects the symmetry and structure of the entire crystal. It defines the arrangement of atoms in a solid and is characterized by its dimensions and angles. Understanding the unit cell is crucial for determining the number of atoms it contains, which can vary based on the type of crystal structure (e.g., face-centered cubic, body-centered cubic).
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Simple Cubic Unit Cell
Atomic Packing Factor (APF)
The Atomic Packing Factor (APF) is a measure of how efficiently atoms are packed in a unit cell. It is calculated as the volume occupied by the atoms in the unit cell divided by the total volume of the unit cell. Different metals have different APFs depending on their crystal structures, which influences their physical properties and density.
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Conversion Factors
Coordination Number
The coordination number is the number of nearest neighbor atoms surrounding a central atom in a crystal structure. It provides insight into the arrangement of atoms and the bonding characteristics within the metal. For example, tungsten has a body-centered cubic structure with a coordination number of 8, indicating that each tungsten atom is surrounded by eight other tungsten atoms.
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Related Practice
Textbook Question
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Textbook Question
An X-ray beam with λ = 154 pm incident on the surface of a crystal produced a maximum reflection at an angle of θ = 28.3°. Assuming n = 1, calculate the separation between layers of atoms in the crystal.
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Textbook Question
Determine the number of atoms per unit cell for each metal.
(a) Polonium
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Textbook Question
Determine the number of atoms per unit cell for each metal.
(c) Nickel
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Textbook Question
Platinum crystallizes with the face-centered cubic unit cell. The radius of a platinum atom is 139 pm. Calculate the edge length of the unit cell and the density of platinum in g/cm3.
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Textbook Question
Molybdenum crystallizes with the body-centered unit cell. The radius of a molybdenum atom is 136 pm. Calculate the edge length of the unit cell and the density of molybdenum
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