Skip to main content
Ch.11 - Chemical Bonding II: Molecular Shapes, VSEPR & MO Theory
Chapter 11, Problem 88b

The structure of acetylsalicylic acid (aspirin) is shown here. How many sigma bonds?

Verified step by step guidance
1
Identify all the atoms in the acetylsalicylic acid molecule. Each carbon (C), hydrogen (H), and oxygen (O) atom can form bonds with other atoms.
Recognize that sigma bonds ( $ sigma $ ) are single covalent bonds between atoms. Each line in the structural formula represents a sigma bond.
Count each line connecting two atoms in the structure as one sigma bond. This includes bonds between C-C, C-H, and C-O.
Do not count double bonds as two sigma bonds; a double bond consists of one sigma bond and one pi bond. Only count the sigma component.
Sum up all the sigma bonds you have counted to get the total number of sigma bonds in the molecule.

Verified Solution

Video duration:
2m
This video solution was recommended by our tutors as helpful for the problem above.
Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Sigma Bonds

Sigma bonds are the strongest type of covalent bond formed by the head-on overlap of atomic orbitals. Each sigma bond allows for free rotation around the bond axis and is characterized by a cylindrical symmetry around the bond. In organic molecules, sigma bonds are typically formed between carbon and other atoms, such as hydrogen or oxygen.
Recommended video:
Guided course
03:26
Lewis Dot Structures: Sigma & Pi Bonds

Molecular Structure

The molecular structure refers to the arrangement of atoms within a molecule, including the types of bonds and the spatial orientation of these atoms. Understanding the molecular structure is crucial for determining the number of sigma bonds, as it helps visualize how atoms are connected and the types of orbitals involved in bonding.
Recommended video:
Guided course
02:08
Molecular Formula

Counting Bonds in Organic Compounds

Counting bonds in organic compounds involves identifying all the covalent bonds present in the molecular structure. Each single bond represents one sigma bond, while double and triple bonds consist of one sigma bond and one or two pi bonds, respectively. This process is essential for understanding the bonding framework of molecules like acetylsalicylic acid.
Recommended video:
Guided course
02:26
Introduction to Organic Chemistry
Related Practice
Textbook Question

Draw an energy diagram for HCl. Predict the bond order and make a sketch of the lowest energy bonding molecular orbital.

1386
views
Textbook Question

The genetic code is based on four different bases with the structures shown here. Assign a geometry and hybridization to each interior atom in these four bases. d. guanine

752
views
Textbook Question

The structure of acetylsalicylic acid (aspirin) is shown here. How many π bonds are present in acetylsalicylic acid?

1012
views
Textbook Question

Most vitamins can be classified as either fat soluble, which results in their tendency to accumulate in the body (so that taking too much can be harmful), or water soluble, which results in their tendency to be quickly eliminated from the body in urine. Examine the structural formulas and space-filling models of these vitamins and determine whether each one is fat soluble (mostly nonpolar) or water soluble (mostly polar). (a) vitamin C

876
views
Textbook Question

Most vitamins can be classified as either fat soluble, which results in their tendency to accumulate in the body (so that taking too much can be harmful), or water soluble, which results in their tendency to be quickly eliminated from the body in urine. Examine the structural formulas and space-filling models of these vitamins and determine whether each one is fat soluble (mostly nonpolar) or water soluble (mostly polar). (c) niacin (vitamin B3)

822
views
Textbook Question

Water does not easily remove grease from dishes or hands because grease is nonpolar and water is polar. The addition of soap to water, however, allows the grease to dissolve. Study the structure of sodium stearate (a soap) and describe how it works.

1244
views