Chapter 9, Problem 86
Write an appropriate Lewis structure for each compound. Make certain to distinguish between ionic and molecular compounds. b. ClF5
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Hydrogenation reactions are used to add hydrogen across double bonds in hydrocarbons and other organic compounds. Use average bond energies to calculate ΔHrxn for the hydrogenation reaction. H2C'CH2( g) + H2( g)¡H3C¬CH3( g)
Ethanol is a possible fuel. Use average bond energies to calculate ΔHrxn for the combustion of ethanol. CH3CH2OH( g) + 3 O2( g)¡2 CO2( g) + 3 H2O( g)
In the Chemistry and the Environment box on free radicals in this chapter, we discussed the importance of the hydroxyl radical in reacting with and eliminating many atmospheric pollutants. However, the hydroxyl radical does not clean up everything. For example, chlorofluorocarbons—which destroy stratospheric ozone—are not attacked by the hydroxyl radical. Consider the hypothetical reaction by which the hydroxyl radical might react with a chlorofluorocarbon: OH( g) + CF2Cl2( g)¡HOF( g) + CFCl2( g) Use bond energies to explain why this reaction is improbable. (The C¬F bond energy is 552 kJ>mol.)
Each compound contains both ionic and covalent bonds. Write ionic Lewis structures for each, including the covalent structure for the ion in brackets. Write resonance structures if necessary. a. BaCO3
Each compound contains both ionic and covalent bonds. Write ionic Lewis structures for each, including the covalent structure for the ion in brackets. Write resonance structures if necessary. c. KNO3
Amino acids are the building blocks of proteins. The simplest amino acid is glycine (H2NCH2COOH). Draw a Lewis structure for glycine. (Hint: The central atoms in the skeletal structure are nitrogen and the two carbon atoms. Each oxygen atom is bonded directly to the right-most carbon atom.)