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Ch.9 - Chemical Bonding I: The Lewis Model
Chapter 9, Problem 107a

Draw the Lewis structure for each compound. a. Cl2O7 (no Cl–Cl bond)

Verified step by step guidance
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Step 1: Count the total number of valence electrons. Chlorine (Cl) has 7 valence electrons and oxygen (O) has 6 valence electrons. Calculate the total for Cl2O7.
Step 2: Determine the central atom. In Cl2O7, chlorine atoms are typically central, with oxygen atoms surrounding them.
Step 3: Arrange the atoms. Place the two chlorine atoms in the center and connect each to three oxygen atoms, ensuring no Cl-Cl bond is formed.
Step 4: Distribute the electrons. Start by placing single bonds between the Cl and O atoms, then distribute the remaining electrons to satisfy the octet rule for each atom, starting with the outer atoms.
Step 5: Check for formal charges and resonance. Adjust the structure by forming double bonds if necessary to minimize formal charges, ensuring the most stable structure.