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Ch.8 - Periodic Properties of the Elements
Chapter 8, Problem 66b

Write the electron configuration for each ion. b. P3-

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Identify the atomic number of phosphorus (P), which is 15, indicating it has 15 electrons in its neutral state.
Determine the electron configuration for a neutral phosphorus atom: 1s^2 2s^2 2p^6 3s^2 3p^3.
Recognize that the P^{3-} ion has gained 3 additional electrons, resulting in a total of 18 electrons.
Write the electron configuration for the P^{3-} ion, which will be the same as the electron configuration for argon (Ar) since it has 18 electrons: 1s^2 2s^2 2p^6 3s^2 3p^6.
Verify that the electron configuration for P^{3-} is complete and matches the noble gas configuration of argon.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Electron Configuration

Electron configuration describes the distribution of electrons in an atom or ion across various energy levels and orbitals. It is typically represented using a notation that indicates the number of electrons in each subshell, such as 1s² 2s² 2p⁶. Understanding electron configuration is essential for predicting chemical behavior and bonding properties.
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Ionic Charge

Ionic charge refers to the electrical charge that an atom or ion carries due to the loss or gain of electrons. For example, a phosphorus atom (P) typically has five valence electrons. When it gains three electrons to form the P³⁻ ion, it achieves a full outer shell, resulting in a negative charge of three. This concept is crucial for determining the electron configuration of ions.
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Valence Electrons

Valence electrons are the outermost electrons of an atom and are involved in chemical bonding. The number of valence electrons determines an element's reactivity and the types of bonds it can form. For phosphorus, which is in group 15 of the periodic table, there are five valence electrons, and understanding this helps in predicting the electron configuration of its ions, such as P³⁻.
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