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Ch.8 - Periodic Properties of the Elements
Chapter 8, Problem 79c,d

Choose the element with the more negative (more exothermic) electron affinity from each pair. c. C or N d. Li or F

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Electron Affinity

Electron affinity is the energy change that occurs when an electron is added to a neutral atom in the gas phase. A more negative electron affinity indicates that the process is more exothermic, meaning energy is released when the atom gains an electron. This property is crucial for understanding how easily an atom can accept an electron and form an anion.
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Trends in Electron Affinity

Electron affinity varies across the periodic table, generally increasing (becoming more negative) from left to right and decreasing down a group. This trend is influenced by atomic size and effective nuclear charge. For example, elements in the same group exhibit less negative electron affinities as you move down due to increased distance from the nucleus and electron shielding.
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Comparison of Carbon and Nitrogen

When comparing carbon (C) and nitrogen (N), it is essential to consider their positions in the periodic table. Nitrogen has a more negative electron affinity than carbon because it is closer to achieving a stable electron configuration (octet) upon gaining an electron. This makes nitrogen more favorable for electron gain, resulting in a more exothermic reaction.
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