Skip to main content
Ch.7 - Quantum-Mechanical Model of the Atom
Chapter 7, Problem 68

According to the quantum-mechanical model for the hydrogen atom, which electron transition produces light with the longer wavelength: 3p → 2s or 4p → 3p?

Verified Solution

Video duration:
3m
This video solution was recommended by our tutors as helpful for the problem above.
Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Electron Transitions

Electron transitions refer to the movement of electrons between different energy levels or orbitals in an atom. When an electron moves from a higher energy level to a lower one, it releases energy in the form of light. The energy of the emitted light corresponds to the difference in energy between the two levels, influencing the wavelength of the light produced.
Recommended video:
Guided course
00:53
Electron Configurations Of Transition Metals Example

Wavelength and Energy Relationship

The wavelength of light is inversely related to its energy, as described by the equation E = hc/λ, where E is energy, h is Planck's constant, c is the speed of light, and λ is wavelength. This means that transitions resulting in lower energy emissions will produce longer wavelengths of light. Understanding this relationship is crucial for determining which electron transition produces light of a longer wavelength.
Recommended video:
Guided course
00:31
Frequency-Wavelength Relationship

Quantum Numbers and Energy Levels

Quantum numbers describe the properties of atomic orbitals and the electrons in those orbitals. The principal quantum number (n) indicates the energy level, while the angular momentum quantum number (l) indicates the shape of the orbital. In the hydrogen atom, transitions between different principal quantum levels (like 2s to 3p or 3p to 4p) determine the energy and wavelength of the emitted light, with higher n values generally corresponding to higher energy levels.
Recommended video:
Guided course
02:55
Principal Quantum Number