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Ch.5 - Gases
Chapter 5, Problem 124

Binary compounds of alkali metals and hydrogen react with water to liberate H2(g). The H2 from the reaction of a sample of NaH with an excess of water fills a volume of 0.490 L above the water. The temperature of the gas is 35 °C and the total pressure is 758 mmHg. Determine the mass of H2 liberated and the mass of NaH that reacted.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Gas Laws

Gas laws describe the behavior of gases in relation to pressure, volume, and temperature. The Ideal Gas Law (PV=nRT) is particularly relevant here, as it allows us to calculate the number of moles of hydrogen gas (H2) produced from the given volume, temperature, and pressure. Understanding these relationships is crucial for determining the amount of gas liberated in the reaction.
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Stoichiometry

Stoichiometry involves the calculation of reactants and products in chemical reactions based on balanced equations. In this case, knowing the stoichiometric relationship between sodium hydride (NaH) and hydrogen gas (H2) is essential to determine how much NaH reacted to produce the measured volume of H2. This concept is fundamental for quantifying the amounts of substances involved in chemical reactions.
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Molar Mass

Molar mass is the mass of one mole of a substance, typically expressed in grams per mole (g/mol). To find the mass of H2 liberated and the mass of NaH that reacted, we need to use the molar mass of hydrogen (approximately 2.02 g/mol) and sodium hydride (approximately 24.99 g/mol). This concept is vital for converting moles of gas into grams, allowing for the calculation of the mass of reactants and products.
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