To what volume should you dilute 50.0 mL of a 12 M stock HNO3 solution to obtain a 0.100 M HNO3 solution?
Ch.4 - Chemical Quantities & Aqueous Reactions
Chapter 4, Problem 67
What is the minimum amount of 6.0 M H2SO4 necessary to produce 25.0 g of H2(g) according to the reaction between aluminum and sulfuric acid? 2 Al(s) + 3 H2SO4(aq) → Al2(SO4)3(aq) + 3 H2(g)
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Determine the molar mass of H_2 by adding the atomic masses of hydrogen atoms.
Calculate the moles of H_2 produced using the formula: moles = mass / molar mass.
Use the stoichiometry of the balanced chemical equation to find the moles of H_2SO_4 needed. According to the equation, 3 moles of H_2SO_4 produce 3 moles of H_2.
Calculate the volume of 6.0 M H_2SO_4 solution required using the formula: volume = moles / molarity.
Ensure the units are consistent and convert the volume to the desired unit if necessary.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Stoichiometry
Stoichiometry is the calculation of reactants and products in chemical reactions based on the balanced chemical equation. It allows us to determine the proportions of substances involved in a reaction, which is essential for converting between grams and moles. In this case, stoichiometry will help us find out how much sulfuric acid is needed to produce a specific mass of hydrogen gas.
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Molarity
Molarity is a measure of concentration defined as the number of moles of solute per liter of solution. It is crucial for understanding how much of a concentrated solution, like 6.0 M H2SO4, is required to achieve a desired amount of product. By knowing the molarity, we can calculate the volume of sulfuric acid needed to react with aluminum to produce the specified amount of hydrogen gas.
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Limiting Reactant
The limiting reactant is the substance that is completely consumed first in a chemical reaction, thus determining the maximum amount of product that can be formed. Identifying the limiting reactant is essential for accurately calculating the quantities of reactants needed. In this scenario, we need to ensure that we have enough sulfuric acid to react with aluminum to produce the desired amount of hydrogen gas.
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Related Practice
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Consider the precipitation reaction: 2 Na3PO4(aq) + 3 CuCl2(aq) → Cu3(PO4)2(s) + 6 NaCl(aq). What volume of 0.175 M Na3PO4 solution is necessary to completely react with 95.4 mL of 0.102 M CuCl2?
Textbook Question
Consider the reaction: Li2S(aq) + Co(NO3)2(aq) → 2 LiNO3(aq) + CoS(s) What volume of 0.150 M Li2S solution is required to completely react with 125 mL of 0.150 M Co(NO3)2?
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Textbook Question
What is the molarity of ZnCl2 that forms when 25.0 g of zinc completely reacts with CuCl2 according to the following reaction? Assume a final volume of 275 mL. Zn(s) + CuCl2(aq) → ZnCl2(aq) + Cu(s)
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Open Question
A 25.0-mL sample of a 1.20 M potassium chloride solution is mixed with 15.0 mL of a 0.900 M lead(II) nitrate solution and this precipitation reaction occurs: 2 KCl(aq) + Pb(NO3)2(aq) → PbCl2(s) + 2 KNO3(aq). The solid PbCl2 is collected, dried, and found to have a mass of 2.45 g. Determine the limiting reactant and the theoretical yield.
Textbook Question
A 25.0-mL sample of a 1.20 M potassium chloride solution is mixed with 15.0 mL of a 0.900 M lead(II) nitrate solution and this precipitation reaction occurs: 2 KCl(aq) + Pb(NO3)2(aq) → PbCl2(s) + 2 KNO3(aq) The solid PbCl2 is collected, dried, and found to have a mass of 2.45 g. Determine the the percent yield.
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