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Ch.4 - Chemical Quantities & Aqueous Reactions
Chapter 4, Problem 106

Many home barbeques are fueled with propane gas (C3H8). What mass of carbon dioxide (in kg) is produced upon the complete combustion of 18.9 L of propane (approximate contents of one 5-gallon tank)? Assume that the density of the liquid propane in the tank is 0.621 g/mL. (Hint: Begin by writing a balanced equation for the combustion reaction.)

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Combustion Reaction

A combustion reaction is a chemical process in which a substance reacts with oxygen to produce heat and light. In the case of propane (C3H8), the balanced equation for its complete combustion is C3H8 + 5 O2 → 3 CO2 + 4 H2O. Understanding this reaction is crucial for determining the products formed and their quantities during the combustion of propane.
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Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions based on the balanced equation. It allows us to determine the amount of carbon dioxide produced from a given volume of propane by using mole ratios derived from the balanced equation. This concept is essential for converting between different units, such as liters of gas to grams of product.
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Density and Volume Conversion

Density is defined as mass per unit volume and is crucial for converting between the volume of a liquid and its mass. In this problem, the density of propane (0.621 g/mL) is used to convert the volume of propane (18.9 L) into mass. This conversion is necessary to apply stoichiometric calculations effectively and find the mass of carbon dioxide produced.
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Related Practice
Open Question
People sometimes use sodium bicarbonate as an antacid to neutralize excess hydrochloric acid in an upset stomach. What mass of hydrochloric acid (in grams) can 2.5 g of sodium bicarbonate neutralize? (Hint: Begin by writing a balanced equation for the reaction between aqueous sodium bicarbonate and aqueous hydrochloric acid.)
Open Question
Toilet bowl cleaners often contain hydrochloric acid, which dissolves the calcium carbonate deposits that accumulate within a toilet bowl. What mass of calcium carbonate (in grams) can be dissolved by 3.8 g of HCl? (Hint: Begin by writing a balanced equation for the reaction between hydrochloric acid and calcium carbonate.)
Textbook Question

The combustion of gasoline produces carbon dioxide and water. Assume gasoline to be pure octane (C8H18) and calculate the mass (in kg) of carbon dioxide that is added to the atmosphere per 1.0 kg of octane burned. (Hint: Begin by writing a balanced equation for the combustion reaction.)

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Textbook Question

Aspirin can be made in the laboratory by reacting acetic anhydride (C4H6O3) with salicylic acid (C7H6O3) to form aspirin (C9H8O4) and acetic acid (C2H4O2). The balanced equation is: C4H6O3 + C7H6O3 → C9H8O4 + C2H4O2 In a laboratory synthesis, a student begins with 3.00 mL of acetic anhydride (density = 1.08 g/mL) and 1.25 g of salicylic acid. Once the reaction is complete, the student collects 1.22 g of aspirin. Determine the limiting reactant. Determine the theoretical yield of aspirin. Determine the percent yield for the reaction.

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Textbook Question

The combustion of liquid ethanol (C2H5OH) produces carbon dioxide and water. After 4.62 mL of ethanol (density = 0.789 g/mL) is allowed to burn in the presence of 15.55 g of oxygen gas, 3.72 mL of water (density = 1.00 g/mL) is collected. Determine the percent yield for the reaction. (Hint: Write a balanced equation for the combustion of ethanol.)

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Textbook Question

A hydrochloric acid solution will neutralize a sodium hydroxide solution. Look at the molecular views showing one beaker of HCl and four beakers of NaOH. Which NaOH beaker will just neutralize the HCl beaker? Begin by writing a balanced chemical equation for the neutralization reaction.

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