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Ch.3 - Molecules, Compounds & Chemical Equations
Chapter 3, Problem 133

Epsom salts is a hydrated ionic compound with the following formula: MgSO4 • x H2O. A 4.93-g sample of Epsom salts is heated to drive off the water of hydration. The mass of the sample after complete dehydration is 2.41 g. Find the number of waters of hydration (x) in Epsom salts.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Hydrated Ionic Compounds

Hydrated ionic compounds, like Epsom salts (MgSO4·xH2O), consist of ionic species combined with water molecules. The 'x' in the formula represents the number of water molecules associated with each formula unit of the ionic compound. Understanding this concept is crucial for determining the amount of water lost during dehydration and calculating the value of 'x'.
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Mass Loss and Stoichiometry

Stoichiometry involves the quantitative relationships between reactants and products in a chemical reaction. In this case, the mass loss during the heating of Epsom salts indicates the amount of water that was present. By applying stoichiometric principles, one can relate the initial mass of the hydrated compound to the mass of the dehydrated compound to find the number of water molecules.
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Molar Mass Calculation

Calculating molar mass is essential for converting between grams and moles of a substance. To find 'x', one must first determine the molar mass of both the hydrated and dehydrated forms of Epsom salts. This calculation allows for the determination of the number of moles of water lost, which directly correlates to the value of 'x' in the hydrated formula.
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Related Practice
Textbook Question

Fructose is a common sugar found in fruit. Elemental analysis of fructose gives the following mass percent composition: C 40.00%, H 6.72%, O 53.28%. The molar mass of fructose is 180.16 g/mol. Find the molecular formula of fructose.

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Textbook Question

Combustion analysis of a 13.42-g sample of equilin (which contains only carbon, hydrogen, and oxygen) produces 39.61 g CO2 and 9.01 g H2O. The molar mass of equilin is 268.34 g/mol. Find its molecular formula.

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Estrone, which contains only carbon, hydrogen, and oxygen, is a female sexual hormone in the urine of pregnant women. Combustion analysis of a 1.893-g sample of estrone produces 5.545 g of CO2 and 1.388 g H2O. The molar mass of estrone is 270.36 g/mol. Find its molecular formula.

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Textbook Question

A hydrate of copper(II) chloride has the following formula: CuCl2 • x H2O. The water in a 3.41-g sample of the hydrate is driven off by heating. The remaining sample has a mass of 2.69 g. Find the number of waters of hydration (x) in the hydrate.

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Textbook Question

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