Use tabulated electrode potentials to calculate ∆G°rxn for each reaction at 25 °C. b. Br2(l) + 2 Cl–(aq) → 2 Br–(aq) + Cl2(g) c. MnO2(s) + 4 H+(aq) + Cu(s) → Mn2+(aq) + 2 H2O(l) + Cu2+(aq)
Ch.19 - Electrochemistry
Chapter 19, Problem 96b,c
Write equations for the half-reactions that occur at the anode and cathode for the electrolysis of each aqueous solution. b. KCl(aq) c. CuBr2(aq)
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Textbook Question
Calculate E°cell for each balanced redox reaction and determine if the reaction is spontaneous as written. b. MnO2(aq) + 4 H+(aq) + Zn(s) → Mn2+(aq) + 2H2O(l) + Zn2+(aq) c. Cl2(g) + 2 F–(aq) → F2(g) + 2 Cl–(aq)
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Textbook Question
Sketch a voltaic cell for each redox reaction. Label the anode and cathode and indicate the half-reaction that occurs at each electrode and the species present in each solution. Also indicate the direction of electron flow.
b. 2 H+(aq) + Fe(s) → H2(g) + Fe2+(aq)
c. 2 NO3–(aq) + 8 H+(aq) + 3 Cu(s) → 2 NO(g) + 4 H2O(l) + 3 Cu2+(aq)
Open Question
Use line notation to represent each electrochemical cell described in Problem 44.
Open Question
The Ksp of Zn(OH)2 is 1.8 * 10^-14. Find Ecell for the half-reaction: Zn(OH)2(s) + 2 e- ⇌ Zn(s) + 2 OH-(aq)
Textbook Question
Balance each redox reaction occurring in acidic aqueous solution. c. BrO3–(aq) + N2H4(g) → Br–(aq) + N2(g)
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