Chapter 18, Problem 96
The values of ΔGf° for the hydrogen halides become less negative with increasing atomic number. The ΔGf° of HI is slightly positive. However, the trend in ΔSf° is to become more positive with increasing atomic number. Explain.
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These reactions are important in catalytic converters in automobiles. Calculate ΔG° for each at 298 K. Predict the effect of increasing temperature on the magnitude of ΔG°. b. 5 H2( g) + 2 NO( g) → 2 NH3( g) + 2 H2O( g)
Calculate ΔG° at 298 K for these reactions and predict the effect on ΔG° of lowering the temperature. b. CaCO3(s) → CaO(s) + CO2( g)
All the oxides of nitrogen have positive values of ΔGf° at 298 K, but only one common oxide of nitrogen has a positive ΔS°f. Identify that oxide of nitrogen without reference to thermodynamic data and explain.
Indicate and explain the sign of ΔSuniv for each process. a. 2 H2( g) + O2( g) → 2 H2O (l ) at 298 K.
A metal salt with the formula MCl2 crystallizes from water to form a solid with the composition MCl2 • 6 H2O. The equilibrium vapor pressure of water above this solid at 298 K is 18.3 mmHg. What is the value of ΔG for the reaction MCl2 • 6 H2O(s) ⇌ MCl2(s) + 6 H2O( g) when the pressure of water vapor is 18.3 mmHg? When the pressure of water vapor is 760 mmHg?