Skip to main content
Ch.18 - Free Energy and Thermodynamics
Chapter 18, Problem 62c

For each reaction, calculate ΔH°rxn, ΔS°rxn, and ΔG°rxn at 25 °C and state whether or not the reaction is spontaneous. If the reaction is not spontaneous, would a change in temperature make it spontaneous? If so, should the temperature be raised or lowered from 25 °C? c. N2(g) + O2(g) → 2 NO(g)

Verified Solution

Video duration:
5m
This video solution was recommended by our tutors as helpful for the problem above.
Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Enthalpy (ΔH°rxn)

Enthalpy change (ΔH°rxn) is the heat absorbed or released during a chemical reaction at constant pressure. It indicates whether a reaction is exothermic (releases heat, ΔH° < 0) or endothermic (absorbs heat, ΔH° > 0). This value is crucial for determining the energy dynamics of the reaction and influences its spontaneity.
Recommended video:
Guided course
02:34
Enthalpy of Formation

Entropy (ΔS°rxn)

Entropy change (ΔS°rxn) measures the disorder or randomness of a system during a reaction. A positive ΔS° indicates an increase in disorder, while a negative ΔS° suggests a decrease. Entropy is a key factor in assessing the spontaneity of a reaction, as reactions tend to favor states of higher entropy.
Recommended video:
Guided course
02:46
Entropy in Thermodynamics

Gibbs Free Energy (ΔG°rxn)

Gibbs Free Energy change (ΔG°rxn) combines enthalpy and entropy to determine the spontaneity of a reaction at constant temperature and pressure. It is calculated using the equation ΔG° = ΔH° - TΔS°. A negative ΔG° indicates a spontaneous reaction, while a positive ΔG° suggests non-spontaneity. The temperature's effect on spontaneity can be analyzed through this relationship.
Recommended video:
Guided course
01:51
Gibbs Free Energy of Reactions
Related Practice
Textbook Question

For each reaction, calculate ΔH°rxn, ΔS°rxn, and ΔG°rxn at 25 °C and state whether or not the reaction is spontaneous. If the reaction is not spontaneous, would a change in temperature make it spontaneous? If so, should the temperature be raised or lowered from 25 °C? d. N2(g) + 3 H2(g) → 2 NH3(g)

1011
views
Open Question
For each reaction, calculate ΔH°_rxn, ΔS°_rxn, and ΔG°_rxn at 25°C and determine whether the reaction is spontaneous. If the reaction is not spontaneous, could a change in temperature make it spontaneous? If so, should the temperature be increased or decreased from 25°C? b. 2 NH3(g) → N2H4(g) + H2(g)
Textbook Question

For each reaction, calculate ΔH°rxn, ΔS°rxn, and ΔG°rxn at 25 °C and state whether or not the reaction is spontaneous. If the reaction is not spontaneous, would a change in temperature make it spontaneous? If so, should the temperature be raised or lowered from 25 °C? a. 2 CH4(g) → C2H6(g) + H2(g)

741
views
Textbook Question

For each reaction, calculate ΔH°rxn, ΔS°rxn, and ΔG°rxn at 25 °C and state whether or not the reaction is spontaneous. If the reaction is not spontaneous, would a change in temperature make it spontaneous? If so, should the temperature be raised or lowered from 25 °C? d. 2 KClO3(s) → 2 KCl(s) + 3 O2(g)

452
views
Textbook Question

Use standard free energies of formation to calculate ΔG° at 25 °C for each reaction in Problem 61. How do the values of ΔG° calculated this way compare to those calculated from ΔH° and ΔS°? Which of the two methods could be used to determine how ΔG° changes with temperature?

2657
views
Open Question
Using standard free energies of formation, calculate ΔG° at 25 °C for each reaction in Problem 62. How do the values of ΔG° calculated this way compare to those calculated from ΔH° and ΔS°? Which of the two methods can determine how ΔG° changes with temperature?