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Ch.17 - Aqueous Ionic Equilibrium
Chapter 17, Problem 50

For each solution, calculate the initial and final pH after adding 0.010 mol of NaOH. a. 250.0 mL of pure water b. 250.0 mL of a buffer solution that is 0.195 M in HCHO2 and 0.275 M in KCHO2 c. 250.0 mL of a buffer solution that is 0.255 M in CH3CH2NH2 and 0.235 M in CH3CH2NH3Cl

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Buffer Solutions

A buffer solution is a system that resists changes in pH upon the addition of small amounts of acid or base. It typically consists of a weak acid and its conjugate base or a weak base and its conjugate acid. In this case, the buffer is made from the weak base CH3CH2NH2 and its conjugate acid CH3CH2NH3Cl, which helps maintain a relatively stable pH when NaOH is added.
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Henderson-Hasselbalch Equation

The Henderson-Hasselbalch equation is a mathematical formula used to calculate the pH of a buffer solution. It is expressed as pH = pKa + log([A-]/[HA]), where [A-] is the concentration of the base and [HA] is the concentration of the acid. This equation is essential for determining the initial and final pH of the buffer after the addition of NaOH, as it allows for the quantification of the ratio of the base and acid components.
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Neutralization Reaction

A neutralization reaction occurs when an acid reacts with a base to form water and a salt, resulting in a change in pH. In this scenario, the addition of NaOH, a strong base, will react with the weak acid component of the buffer, CH3CH2NH3Cl, leading to a decrease in the concentration of the acid and an increase in the concentration of the base. Understanding this reaction is crucial for calculating the final pH of the buffer solution.
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