Chapter 15, Problem 40
Consider the reaction: SO2Cl2(g) ⇌ SO2(g) + Cl2(g) Kp = 2.91*10^3 at 298 K In a reaction at equilibrium, the partial pressure of SO2 is 137 torr and that of Cl2 is 285 torr. What is the partial pressure of SO2Cl2 in this mixture?
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Consider the reaction: N (g) + 3H (g) ⇌ 2NH (g) Complete the table. Assume that all concentrations are equilib- rium concentrations in M. T (K) [n2] [H2] [nH3] Kc 500 0.115 0.105 0.439 575 0.110 ________ 0.128 775 0.120 0.140 ________ ________ 9.6 0.0584
Consider the following reaction: H2(g) + I2(g) ⇌ 2 HI(g) Complete the table. Assume that all concentrations are equilib- rium concentrations in M. T (°C) [H2] [i2] [Hi] Kc 25 0.0355 0.0388 340 ________ 0.0455 445 0.0485 0.0468 0.922 ________ 0.387 9.6 ________ 50.2
Consider the reaction: 2NO(g) + Br2(g) ⇌ 2NOBr(g) Kp = 28.4 at 298K In a reaction mixture at equilibrium, the partial pressure of NO is 108 torr and that of Br2 is 126 torr. What is the partial pressure of NOBr in this mixture?
Consider the reaction: NH4HS(s) ⇌ NH3(g) + H2S(g) At a certain temperature, Kc = 8.5 * 10 - 3. A reaction mixture at this temperature containing solid NH4HS has [NH3] = 0.166 M and [H2S] = 0.166 M. Will more of the solid form or will some of the existing solid decompose as equilibrium is reached?
Silver sulfate dissolves in water according to the reaction: Ag2SO4(s) ⇌ 2Ag+(aq) + SO42-(aq) Kc = 1.1 * 10-5 at298K A 1.5-L solution contains 6.55 g of dissolved silver sulfate. If addi- tional solid silver sulfate is added to the solution, will it dissolve?
Consider the reaction and the associated equilibrium constant: aA(g) ⇌ bB(g) Kc = 4.0 Find the equilibrium concentrations of A and B for each value of a and b. Assume that the initial concentration of A in each case is 1.0 M and that no B is present at the beginning of the reaction. c. a=1;b=2