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Ch.15 - Chemical Equilibrium

Chapter 15, Problem 40

Consider the reaction: SO2Cl2(g) ⇌ SO2(g) + Cl2(g) Kp = 2.91*10^3 at 298 K In a reaction at equilibrium, the partial pressure of SO2 is 137 torr and that of Cl2 is 285 torr. What is the partial pressure of SO2Cl2 in this mixture?

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Hello everyone today. We are being given the following problem and asked to solve for it. So it says the equilibrium constant K. P. For the oxidation of nitric oxide is 1152 at 1 50 degrees Celsius. Were then given the following chemical reaction In that reaction mixture at equilibrium oxygen has a partial pressure of .345 atmospheres. While the partial pressure of nitrogen dioxide is .225 atmospheres were then asked to calculate the partial pressure of nitric oxide at equilibrium. So the first thing we want to do does he want to calculate, we want to write out our K. P. For the expression below. So R. K. P. It's going to be equal to the pressures of our products over reactivates. And so putting this together, We have our pressure of our only product which is nitrogen dioxide in 02. And since there is a two coefficient we're going to make this exponent into a. two and our denominator we have to react. It's present. We have nitric oxide and so we have the pressure of N. O. Nitric oxide and that has a two coefficient as well. So we're going to give that an exponent of two. And lastly we're going to multiply the second reactant from by the first one which is just molecular oxygen. And so we have our K. P. Expression below. We also were given a partial pressure of oxygen and the partial pressure of pressure of nitrogen dioxide. And so ultimately we want to find the partial pressure of nitric oxide. So we're gonna label that X. And so Plugging our values in to this reaction that we just found we have our K. P. or equilibrium constant being 1,152. And that's going to equal Our partial pressure of our nitrogen dioxide. Which in the question Stem said that it was 0.225 atmospheres. And we're going to square that and then we're going to divide that by our partial pressure of nitric oxide, which we don't know. So we're just gonna say X. And we're gonna square that as well. And then our partial pressure for molecular oxygen or 02 is 0.345 atmospheres, solving for X. We get an X. is equal to 0.0113 atmospheres. In other words, this is our partial pressure of nitric oxide. I hope this helped. And until next time.
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