Chapter 14, Problem 86
Consider the reaction: 2 O3(g) → 3 O2( g) The rate law for this reaction is: Rate = k [O3]2 [O2] Suppose that a 1.0-L reaction vessel initially contains 1.0 mol of O3 and 1.0 mol of O2. What fraction of the O3 will have reacted when the rate falls to one-half of its initial value?
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The tabulated data were collected for this reaction at 500 °C: CH3CN(g) → CH3NC( g) b. What is the half-life for this reaction (at the initial concentration)?
The tabulated data were collected for this reaction at a certain temperature: X2Y → 2 X + Y a. Determine the order of the reaction and the value of the rate constant at this temperature.
The tabulated data were collected for this reaction at a certain temperature: X2Y → 2 X + Y c. What is the concentration of X after 10.0 hours?
Dinitrogen pentoxide decomposes in the gas phase to form nitrogen dioxide and oxygen gas. The reaction is first order in dinitrogen pentoxide and has a half-life of 2.81 h at 25 °C. If a 1.5-L reaction vessel initially contains 745 torr of N2O5 at 25 °C, what partial pressure of O2 is present in the vessel after 215 minutes?
Iodine atoms combine to form I2 in liquid hexane solvent with a rate constant of 1.5⨉1010 L/mols. The reaction is second order in I. Since the reaction occurs so quickly, the only way to study the reaction is to create iodine atoms almost instantaneously, usually by photochemical decomposition of I2. Suppose a flash of light creates an initial [I] concentration of 0.0100 M. How long will it take for 95% of the newly created iodine atoms to recombine to form I2?
Consider this energy diagram:
a. How many elementary steps are involved in this reaction?