Chapter 14, Problem 40a
A reaction in which A, B, and C react to form products is zero order in A, one-half order in B, and second order in C. a. Write a rate law for the reaction.
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This reaction is first order in N2O5: N2O5(g) → NO3(g) + NO2(g) The rate constant for the reaction at a certain temperature is 0.053/s. b. What would the rate of the reaction be at the concentration indicated in part a if the reaction were second order? Zero order? (Assume the same numerical value for the rate constant with the appropriate units.)
A reaction in which A, B, and C react to form products is first order in A, second order in B, and zero order in C. b. What is the overall order of the reaction?
A reaction in which A, B, and C react to form products is first order in A, second order in B, and zero order in C c. By what factor does the reaction rate change if [A] is doubled (and the other reactant concentrations are held constant)?
A reaction in which A, B, and C react to form products is zero order in A, one-half order in B, and second order in C. e. By what factor does the reaction rate change if [C] is doubled (and the other reactant concentrations are held constant)?
Consider the tabulated data showing the initial rate of a reaction (A → products) at several different concentrations of A. What is the order of the reaction? Write a rate law for the reaction including the value of the rate constant, k.
The tabulated data were collected for this reaction: CH3Cl( g) + 3 Cl2( g) ¡ CCl4( g) + 3 HCl( g
Write an expression for the reaction rate law and calculate the value of the rate constant, k. What is the overall order of the reaction?