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Ch.13 - Solutions
Chapter 13, Problem 64e

A solution is prepared by dissolving 20.2 mL of methanol (CH3OH) in 100.0 mL of water at 25 °C. The final volume of the solution is 118 mL. The densities of methanol and water at this temperature are 0.782 g/mL and 1.00 g/mL, respectively. For this solution, calculate the concentration in each unit. e. mole percent

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Molarity and Concentration Units

Molarity is a common way to express concentration, defined as the number of moles of solute per liter of solution. In addition to molarity, concentrations can also be expressed in terms of mole percent, which indicates the ratio of moles of a specific component to the total moles of all components in the solution, multiplied by 100. Understanding these units is essential for accurately calculating and comparing concentrations.
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Density and Mass Calculation

Density is the mass of a substance per unit volume, typically expressed in grams per milliliter (g/mL). To find the mass of a liquid from its volume and density, the formula mass = density × volume is used. This concept is crucial for converting the volume of methanol and water into mass, which is necessary for calculating the number of moles and ultimately the concentration.
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Molar Mass Calculation Example

Mole Concept

The mole is a fundamental unit in chemistry that quantifies the amount of substance. One mole contains approximately 6.022 x 10²³ entities (Avogadro's number), allowing chemists to relate mass to the number of particles. In this context, calculating the number of moles of methanol and water is essential for determining their contributions to the mole percent of the solution.
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Related Practice
Textbook Question

A solution is prepared by dissolving 20.2 mL of methanol (CH3OH) in 100.0 mL of water at 25 °C. The final volume of the solution is 118 mL. The densities of methanol and water at this temperature are 0.782 g/mL and 1.00 g/mL, respectively. For this solution, calculate the concentration in each unit. b. molality

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Textbook Question

A solution is prepared by dissolving 20.2 mL of methanol (CH3OH) in 100.0 mL of water at 25 °C. The final volume of the solution is 118 mL. The densities of methanol and water at this temperature are 0.782 g/mL and 1.00 g/mL, respectively. For this solution, calculate the concentration in each unit. c. percent by mass

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Textbook Question

A solution is prepared by dissolving 20.2 mL of methanol (CH3OH) in 100.0 mL of water at 25 °C. The final volume of the solution is 118 mL. The densities of methanol and water at this temperature are 0.782 g/mL and 1.00 g/mL, respectively. For this solution, calculate the concentration in each unit. d. mole fraction

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Textbook Question

Household hydrogen peroxide is an aqueous solution containing 3.0% hydrogen peroxide by mass. What is the molarity of this solution? (Assume a density of 1.01 g/mL.)

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Textbook Question

One brand of laundry bleach is an aqueous solution containing 4.55% sodium hypochlorite (NaOCl) by mass. What is the molarity of this solution? (Assume a density of 1.02 g/mL.)

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Textbook Question

An aqueous solution contains 36% HCl by mass. Calculate the molality and mole fraction of the solution.

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