In each pair of compounds, pick the one with the higher vapor pressure at a given temperature. Explain your reasoning. a. CH4 or CH3Cl c. CH3OH or H2CO
Ch.11 - Liquids, Solids & Intermolecular Forces
Chapter 11, Problem 45d
Determine whether each pair of compounds forms a homogeneous solution when combined. For those that form homogeneous solutions, indicate the type of forces that are involved. d. CH3CH2OH and H2O
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Identify the polarity of each compound: CH<sub>3</sub>CH<sub>2</sub>OH (ethanol) is a polar molecule due to the presence of the hydroxyl group (-OH), and H<sub>2</sub>O (water) is also a polar molecule.
Consider the 'like dissolves like' principle in chemistry, which states that polar substances tend to dissolve well in other polar substances.
Since both ethanol and water are polar, they are likely to form a homogeneous solution when mixed.
Determine the type of intermolecular forces involved: Both ethanol and water can form hydrogen bonds due to the presence of hydrogen directly bonded to electronegative atoms (oxygen in both cases).
Conclude that ethanol and water will form a homogeneous solution primarily through hydrogen bonding.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Polarity
Polarity refers to the distribution of electrical charge over the atoms in a molecule. Molecules with significant differences in electronegativity between their atoms, such as water (H2O) and ethanol (CH3CH2OH), exhibit polar characteristics. This polarity affects how substances interact with each other, influencing their ability to mix and form homogeneous solutions.
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Intermolecular Forces
Intermolecular forces are the forces of attraction or repulsion between neighboring particles (atoms, molecules, or ions). In the case of CH3CH2OH and H2O, hydrogen bonding plays a crucial role, as both compounds can form hydrogen bonds due to the presence of hydroxyl (-OH) groups. These forces are essential for determining whether two substances will mix uniformly.
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Solubility
Solubility is the ability of a substance to dissolve in a solvent, forming a homogeneous solution. The principle of 'like dissolves like' suggests that polar solvents, such as water, are more likely to dissolve polar solutes, like ethanol. Understanding solubility helps predict whether two compounds will form a homogeneous mixture when combined.
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Related Practice
Textbook Question
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Textbook Question
In each pair of compounds, pick the one with the higher vapor pressure at a given temperature. Explain your reasoning. b. CH3CH2CH2OH or CH3OH
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Textbook Question
Determine whether each pair of compounds forms a homogeneous solution when combined. For those that form homogeneous solutions, indicate the type of forces that are involved. a. CCl4 and H2O b. KCl and H2O c. Br2 and CCl4
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Textbook Question
Determine whether each pair of compounds forms a homogeneous solution when combined. For those that form homogeneous solutions, indicate the type of forces that are involved. a. CH3CH2CH2CH2CH3 and CH3CH2CH2CH2CH2CH3 b. CBr4 and H2O c. LiNO3 and H2O d. CH3OH and CH3CH2CH2CH2CH3
Textbook Question
Which compound would you expect to have greater surface tension: acetone [(CH3)2CO] or water (H2O)? Explain.
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Open Question
Why does water wet some surfaces and bead up on others, while mercury beads up on almost all surfaces?