Ch.9 - Thermochemistry: Chemical Energy
Chapter 9, Problem 108
Styrene (C8H8), the precursor of polystyrene polymers, has a standard heat of combustion of -4395 kJ/mol. Write a balanced equation for the combustion reaction, and calculate ΔH°f for styrene in kJ/mol. ΔH°f [CO2(g)] = -393.5 kJ/mol; ΔH°f [H2O(l)] = -285.8 kJ/mol
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Textbook Question
Calculate ∆H°f in kJ/mol for benzene, C6H6, from the following data: 2 C6H6(l) + 15 O2(g) → 12 CO2(g) + 6 H2O(l) ∆H°=-6534 kJ ∆H°f (CO2) = -393.5 kJ/mol ∆H°f(H2O) = -285.8 kJ/mol
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Textbook Question
The standard enthalpy change for the reaciton of SO3(g) with H2O(l) to yield H2SO4(aq) is ΔH° = -227.8 kJ. Use the information in Problem 9.104 to calculate ΔH°f for H2SO4(aq) in kJ/mol. [For H2O(l), ΔH°f = -285.88 kJ/mol.]
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Textbook Question
Acetic acid (CH3CO2H), whose aqueous solutions are known as vinegar, is prepared by reaction of ethyl alcohol (CH3CH2OH) with oxygen: CH3CH2OH(l) + O2(g) → CH3CO2H(l) + H2O(l) Use the following data to calculate ∆H° in kilojoules for the reaction: ∆H°f [CH3CH2OH(l)] = -277.7 kJ/mol ∆H°f [CH3CO2H(l)] = -484.5 kJ/mol ∆H°f [H2O(l)] = -285.8 kJ/mol
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Textbook Question
Methyl tert-butyl ether (MTBE), C5H12O, a gasoline additive used to boost octane ratings, has ΔH°f = -313.6 kJ/mol. Write a balanced equaiton for its combustion reaciton, and calcualte its standard heat of combustion in kilojoules
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Textbook Question
Methyl tert-butyl ether (MTBE) is prepared by reaciton of methanol (l) (ΔH°f = -239.2 kJ/mol) with 2-methyl-propene (g), according to the requation Calculate ΔH°f in kJ/mol for 2-methylpropene
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Textbook Question
Answer the following questions.
(e) A gallon of ice cream contains exactly 32 servings, and each serving has 165 Calories, of which 30.0% are derived from fat. How many Calories derived from fat would you consume if you ate one half of a gallon of ice cream?
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