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Ch.8 - Covalent Compounds: Bonding Theories and Molecular Structure
Chapter 8, Problem 113

The dichromate ion, Cr2O72-, has neither Cr¬Cr nor O¬O bonds. (b) How many outer-shell electrons does each Cr atom have in your electron-dot structure? What is the likely geometry around the Cr atoms?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Electron Configuration

The electron configuration of an atom describes the distribution of its electrons among the various orbitals. For chromium (Cr), the electron configuration is [Ar] 3d5 4s1, indicating that it has six outer-shell electrons in its valence shell. Understanding this configuration is essential for determining the number of outer-shell electrons in the dichromate ion.
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Electron Configuration Example

Lewis Structures

Lewis structures are diagrams that represent the bonding between atoms and the lone pairs of electrons in a molecule. In the case of the dichromate ion, drawing the Lewis structure helps visualize the arrangement of electrons around the chromium atoms, which is crucial for answering how many outer-shell electrons each Cr atom has.
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Molecular Geometry

Molecular geometry refers to the three-dimensional arrangement of atoms in a molecule. The geometry around the chromium atoms in the dichromate ion can be predicted using VSEPR theory, which states that electron pairs will arrange themselves to minimize repulsion. In this case, the geometry is typically described as tetrahedral due to the presence of four oxygen atoms surrounding the chromium atoms.
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Related Practice
Textbook Question

Carbon monoxide is produced by incomplete combustion of fossil fuels. (c) What is the bond order of CO? Does this match the bond order predicted by the electron-dot structure?

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Textbook Question
Make a sketch showing the location and geometry of the p orbitals in the nitrite ion, NO2-. Describe the bonding in this ion using a localized valence bond model for s bonding and a delocalized MO model for p bonding.
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Textbook Question
In the cyanate ion, OCN-, carbon is the central atom. (d) Which hybrid orbitals are used by the C atom, and how many p bonds does the C atom form?
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Textbook Question

Cyclooctatetraene dianion, C8H82-, is an organic ion with the structure shown. Considering only the p bonds and not the s bonds, cyclooctatetraene dianion can be described by the following energy diagrams of its p molecular orbitals:

(a) What is the hybridization of the 8 carbon atoms?

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Textbook Question

Cyclooctatetraene dianion, C8H82-, is an organic ion with the structure shown. Considering only the p bonds and not the s bonds, cyclooctatetraene dianion can be described by the following energy diagrams of its p molecular orbitals:

(b) Three of the p molecular orbitals are bonding, three are antibonding, and two are nonbonding, meaning that they have the same energy level as isolated p orbitals. Which is which?

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Textbook Question

Cyclooctatetraene dianion, C8H82-, is an organic ion with the structure shown. Considering only the p bonds and not the s bonds, cyclooctatetraene dianion can be described by the following energy diagrams of its p molecular orbitals:

(c) Complete the MO energy diagram by assigning the appropriate numbers of p electrons to the various molecular orbitals, indicating the electrons using up/down arrows 1c T2.

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