Ch.8 - Covalent Compounds: Bonding Theories and Molecular Structure
All textbooksMcMurry 8th EditionCh.8 - Covalent Compounds: Bonding Theories and Molecular StructureProblem 102
Chapter 8, Problem 102
Look at the MO diagrams of corresponding neutral diatomic species in Figure 8.22, and predict whether each of the following ions is diamagnetic or paramagnetic. Diagrams for Li2 and C2 are similar to N2; Cl2 is similar to F2. (c) F2-
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Related Practice
Textbook Question
For a given type of MO, use a s2s as an example, is the
bonding or antibonding orbital higher in energy? Explain.
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Textbook Question
Use the MO energy diagram in Figure 8.22b to describe the
bonding in O2+, O2, and O2-. Which of the three is likely to
be stable? What is the bond order of each? Which contain
unpaired electrons?
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Textbook Question
The C2 molecule can be represented by an MO diagram similar
to that in Figure 8.22a.
(b) To increase the bond order of C2, should you add or
remove an electron?
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Textbook Question
Calcium carbide, CaC2, reacts with water to produce acetylene,
C2H2, and is sometimes used as a convenient source of
that substance. Use the MO energy diagram in Figure 8.22a
to describe the bonding in the carbide anion, C22-. What is
its bond order?
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Textbook Question
At high temperatures, sulfur vapor is predominantly in the form of S2(g) molecules. (a) Assuming that the molecular orbitals for third-row diatomic molecules are analogous to those for second-row molecules, construct an MO diagram for the valence orbitals of S2(g).
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Textbook Question
At high temperatures, sulfur vapor is predominantly in the form of S2(g) molecules. (d) When two electrons are added to S2, the disulfide ion S22- is formed. Is the bond length in S22- likely to be shorter or longer than the bond length in S2? Explain.
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