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Ch.8 - Covalent Compounds: Bonding Theories and Molecular Structure
Chapter 8, Problem 107b

Carbon monoxide is produced by incomplete combustion of fossil fuels. (b) Do you expect CO to be paramagnetic or diamagnetic?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Paramagnetism and Diamagnetism

Paramagnetism occurs in substances that have unpaired electrons, which create a net magnetic moment, allowing them to be attracted to magnetic fields. In contrast, diamagnetism is exhibited by substances with all paired electrons, resulting in no net magnetic moment, causing them to be weakly repelled by magnetic fields. Understanding these properties is essential for predicting the magnetic behavior of molecules.
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Molecular Orbital Theory

Molecular Orbital Theory explains how atomic orbitals combine to form molecular orbitals, which can be occupied by electrons. In this theory, electrons are distributed among bonding, antibonding, and non-bonding orbitals. The arrangement of electrons in these orbitals determines whether a molecule is paramagnetic or diamagnetic, based on the presence of unpaired electrons.
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Electron Configuration of Carbon Monoxide (CO)

Carbon monoxide (CO) consists of one carbon atom and one oxygen atom, and its electron configuration can be analyzed using molecular orbital theory. In CO, the molecular orbitals are filled according to the Aufbau principle, leading to a configuration where there is one unpaired electron in a π* antibonding orbital. This unpaired electron is what makes CO paramagnetic, as it contributes to a net magnetic moment.
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