Ch.7 - Covalent Bonding and Electron-Dot Structures
Chapter 7, Problem 92
Some mothballs used when storing clothes are made of naphthalene (C10H8), which has the following incomplete structure.
(a) Add double bonds where needed to draw a complete electron-dot structure.Verified Solution
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Related Practice
Textbook Question
The estimated lattice energy for CsF21s2 is +2347 kJ/mol. Use the data given in Problem 6.86 to calculate an overall energy change in kilojoules per mole for the formation of CsF21s2 from its elements. Does the overall reaction absorb energy or release it? In light of your answer to Problem 6.86, which compound is more likely to form in the reaction of cesium with fluorine, CsF or CsF2?
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Textbook Question
Benzene has the following structural formula.
(b) Which statement best describes the carbon–carbon bonds in benzene?
(i) Three carbon–carbon bonds are longer and weaker than the other three carbon–carbon bonds.
(ii) All six carbon–carbon bonds are identical, and their length and strength are between a double and single bond.
(iii) The length of carbon–carbon double bond switches back and forth between the length of a double and a single bond.
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Textbook Question
Draw three resonance structures for sulfur tetroxide, SO4, whose connections are shown below. (This is a neutral mol-ecule; it is not a sulfate ion.) Assign formal charges to the atoms in each structure.
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Textbook Question
Four different structures (a), (b), (c), and (d) can be drawn for compounds named dibromobenzene, but only three different compounds actually exist. Explain.
(a)
(b)
(c)
(d)
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Textbook Question
Use the following information plus the data given in Tables 6.2 and 6.3 to calculate the second electron affinity, Eea2, of oxygen. Is the O2-ion stable in the gas phase? Why is it stable in solid MgO?
Heat of sublimation for Mg1s2 = +147.7 kJ/mol
Bond dissociation energy for O21g2 = +498.4 kJ/mol
Eea1 for O1g2 = -141.0 kJ/mol
Net energy change for formation of MgO(s) from its elements = -601.7 kJ/mol
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Textbook Question
Assign formal charges to the atoms in the following structures. Which of the two do you think is the more important contributor to the resonance hybrid?(a)(b)
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