Skip to main content
Ch.7 - Covalent Bonding and Electron-Dot Structures
Chapter 7, Problem 85d

Draw as many resonance structures as you can for the following nitrogen-containing compounds. Not all will obey the octet rule. Use curved arrows to depict the conversion of one structure into another. (d) N2O3(ONNO2)

Verified Solution

Video duration:
6m
This video solution was recommended by our tutors as helpful for the problem above.
Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Resonance Structures

Resonance structures are different ways of drawing the same molecule that illustrate the delocalization of electrons. They are used to represent molecules where a single Lewis structure cannot adequately depict the electron distribution. Each resonance structure contributes to the overall hybrid structure, which is a more accurate representation of the molecule's actual electron configuration.
Recommended video:
Guided course
01:42
Resonance Structures

Octet Rule

The octet rule is a chemical guideline stating that atoms tend to bond in such a way that they each have eight electrons in their valence shell, achieving a stable electron configuration similar to that of noble gases. While many elements follow this rule, some, particularly transition metals and heavier elements, can have expanded octets or may not complete their octet, leading to exceptions in resonance structures.
Recommended video:

Curved Arrows in Resonance

Curved arrows are a notation used in organic chemistry to show the movement of electrons during the formation of resonance structures. The tail of the arrow indicates the starting point of the electron pair, while the head points to where the electrons are moving. This visual representation helps in understanding how different resonance forms are interrelated and how electron delocalization occurs within a molecule.
Recommended video:
Guided course
01:42
Resonance Structures
Related Practice
Textbook Question
Calculate the energy change in kilojoules per mole when lithium atoms lose an electron to bromine atoms to form isolated Li+ and Br-ions. [The Ei for Li1g2 is 520 kJ/mol; the Eea for Br1g2 is -325 kJ/mol.] Will a lithium atom transfer an elec-tron to a bromine atom to form isolated Li+ 1g2 and Br-1g2 ions? Explain.
478
views
Textbook Question
Ibuprofen 1C13H18O22, marketed under such brand names as Advil and Motrin, is a drug sold over the counter for treatment of pain and inflammation. Complete the structure of ibuprofen by adding hydrogen atoms and lone pairs where needed.

964
views
Textbook Question

Draw as many resonance structures as you can for the following nitrogen-containing compounds. Not all will obey the octet rule. Use curved arrows to depict the conversion of one structure into another. (b) NO

512
views
Textbook Question
Which of the following pairs of structures represent resonance forms, and which do not? (a)
762
views
Textbook Question
The estimated lattice energy for CsF21s2 is +2347 kJ/mol. Use the data given in Problem 6.86 to calculate an overall energy change in kilojoules per mole for the formation of CsF21s2 from its elements. Does the overall reaction absorb energy or release it? In light of your answer to Problem 6.86, which compound is more likely to form in the reaction of cesium with fluorine, CsF or CsF2?

1064
views
Textbook Question
Benzene has the following structural formula.

(b) Which statement best describes the carbon–carbon bonds in benzene? (i) Three carbon–carbon bonds are longer and weaker than the other three carbon–carbon bonds. (ii) All six carbon–carbon bonds are identical, and their length and strength are between a double and single bond. (iii) The length of carbon–carbon double bond switches back and forth between the length of a double and a single bond.
422
views