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Ch.6 - Ionic Compounds: Periodic Trends and Bonding Theory
Chapter 6, Problem 8

Which of the following processes will release the most energy? (LO 6.9) (a) (b) (c) (d)

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Identify the type of processes listed in options (a), (b), (c), and (d). These could be chemical reactions, phase changes, or other energy-related transformations.
Determine the nature of each process, whether it is exothermic or endothermic. Exothermic processes release energy, while endothermic processes absorb energy.
For each exothermic process, consider the amount of energy typically released. This can often be found in tables of standard enthalpy changes or can be estimated based on the types of bonds formed or broken.
Compare the energy changes associated with each process. The process that releases the most energy will typically have the largest negative enthalpy change (ΔH).
Conclude by selecting the option that corresponds to the process with the highest energy release, based on the calculated or estimated enthalpy changes.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Exothermic Reactions

Exothermic reactions are chemical processes that release energy, usually in the form of heat, to the surroundings. This occurs when the total energy of the products is lower than that of the reactants, resulting in a net release of energy. Common examples include combustion reactions, where fuels react with oxygen to produce carbon dioxide and water, releasing significant energy.
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Endothermic & Exothermic Reactions

Enthalpy Change (ΔH)

Enthalpy change, denoted as ΔH, is a measure of the total heat content of a system. In chemical reactions, a negative ΔH indicates that energy is released (exothermic), while a positive ΔH indicates energy is absorbed (endothermic). Understanding ΔH is crucial for predicting the energy changes associated with different processes and determining which will release the most energy.
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Enthalpy of Formation

Bond Energy

Bond energy refers to the amount of energy required to break a bond between two atoms. When chemical bonds are formed during a reaction, energy is released, and the total energy released is related to the bond energies of the reactants and products. A process that involves the formation of strong bonds and the breaking of weaker bonds will typically release more energy, making bond energy a key factor in evaluating energy release in reactions.
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Related Practice
Textbook Question
Which of the following processes requires the largest input of energy? (LO 6.5) (a) (b) (c) (d)
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Open Question
Phosphorus has a __________ ionization energy than magnesium because __________. (LO 6.5, 6.6) (a) larger; the electron in phosphorus is in a higher n level than the electron in magnesium (b) larger; the electron in phosphorus has a higher Zeff than the electron in magnesium (c) smaller; the electron in phosphorus is in a lower n level than the electron in magnesium (d) smaller; the electron in phosphorus has a lower Zeff than the electron in magnesium
Textbook Question
The successive ionization energies for a second-period element are given. What is the identity of the element? (LO 6.8) Ea1 = 1402 kJ/mol Ea2 = 2856 kJ/mol Ea3 = 4578 kJ/mol Ea4 = 7475 kJ/mol Ea5 = 9445 kJ/mol Ea6 = 53,266 kJ/mol Ea7 = 64,630 kJ/mol (a) Be (b) C (c) N (d) F
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Textbook Question
Elements that have large negative electron affinities generally have (LO 6.10) (a) high values for Zeff and a vacancy in a valence orbital. (b) low values for Zeff and a vacancy in a valence orbital. (c) high values for Zeff and filled valence orbitals. (d) low values for Zeff and filled valence orbitals.
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Textbook Question

Predict the formula of the ionic compound that forms between potassium and sulfur. (LO 6.11) (a) KS (b) KS2 (c) K2S2 (d) K2S

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Textbook Question

Which molecular scale image best represents the ionic com-pound that forms between cesium and chlorine? (Cesium is represented by red circles, and chlorine is represented by blue circles.) (LO 6.12) (a)

(b)

(c)

(d)

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