Ch.6 - Ionic Compounds: Periodic Trends and Bonding Theory
All textbooksMcMurry 8th EditionCh.6 - Ionic Compounds: Periodic Trends and Bonding TheoryProblem 103
Chapter 6, Problem 103
Consider the electronic structure of the element bismuth. (d) Would you expect element 115 to have an ionization ene-rgy greater than, equal to, or less than that of bismuth? Explain.
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Order the electrons in the following orbitals according to their shielding ability: 4s, 4d, 4f.
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Many early chemists noted a diagonal relationship among ele-ments in the periodic table, whereby a given element is some-times more similar to the element below and to the right than it is to the element directly below. Lithium is more similar to magnesium than to sodium, for example, and boron is more similar to silicon than to aluminum. Use your knowledge about the periodic trends of such properties as atomic radii and Zeff to explain the existence of diagonal relationships.
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Heating elemental cesium and platinum together for two days at 973 K gives a dark red ionic compound that is 57.67% Cs and 42.33% Pt.
(c) What are the charge and electron configuration of the platinum ion?
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Textbook Question
Consider the electronic structure of the element bismuth. (a) The first ionization energy of bismuth is Ei1 = +703 kJ/ mol. What is the longest possible wavelength of light that could ionize an atom of bismuth?
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Iron is commonly found as Fe, Fe2+, and Fe3+. (b) What are the n and l quantum numbers of the electron removed on going from Fe2+ to Fe3+?
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Iron is commonly found as Fe, Fe2++, and Fe3+. (c) The third ionization energy of Fe is Ei3 = +2952 kJ/mol. What is the longest wavelength of light that could ionize Fe2+(g) to Fe3+(g)?
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