A 250.0 g sample of a white solid is known to be a mixture of KNO3, BaCl2, and NaCl. When 100.0 g of this mixture is dis-solved in water and allowed to react with excess H2SO4, 67.3 g of a white precipitate is collected. When the remaining 150.0 g of the mixture is dissolved in water and allowed to react with excess AgNO3, 197.6 g of a second precipitate is collected. (a) What are the formulas of the two precipitates?
Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 95
Why do we use a double arrow to show the dissociation of a weak acid or weak base in aqueous solution?
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Equilibrium in Chemical Reactions
In chemical reactions, especially those involving weak acids and bases, equilibrium refers to the state where the forward and reverse reactions occur at the same rate. This means that the concentrations of reactants and products remain constant over time. The double arrow indicates that both the dissociation and recombination processes are happening simultaneously, reflecting the dynamic nature of the reaction.
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Weak Acids and Bases
Weak acids and bases are substances that do not completely dissociate in solution. Unlike strong acids and bases, which fully ionize, weak acids and bases establish an equilibrium between the undissociated and dissociated forms. This incomplete dissociation is why we use a double arrow, as it signifies that the reaction can proceed in both directions.
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Le Chatelier's Principle
Le Chatelier's Principle states that if a system at equilibrium is disturbed, the system will adjust to counteract the disturbance and restore a new equilibrium. In the context of weak acids and bases, changes in concentration, temperature, or pressure can shift the position of equilibrium, affecting the extent of dissociation. This principle helps explain the behavior of weak acids and bases in solution.
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Related Practice
Textbook Question
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Textbook Question
(b) What is the mass of each substance in the original 250 g mixture?
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Assume that you are given a solution of an unknown acid or base. How can you tell whether the unknown substance is acidic or basic?
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Write balanced ionic equations for the following reactions. (a) Aqueous perchloric acid is neutralized by aqueous calcium hydroxide.
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Write balanced ionic equations for the following reactions. (b) Aqueous sodium hydroxide is neutralized by aqueous acetic acid.
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Write balanced ionic equations for the following reactions. (a) Aqueous hydrobromic acid is neutralized by aqueous calcium hydroxide.
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