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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 135a

A compound with the formula XOCl2 reacts with water, yielding HCl and another acid H2XO3, which has two acidic hydrogens that react with NaOH. When 0.350 g of XOCl2 was added to 50.0 mL of water and the resultant solution was titrated, 96.1 mL of 0.1225 M NaOH was required to react with all the acid. (a) Write a balanced equation for the reaction of XOCl2 with H2O.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Balancing Chemical Equations

Balancing chemical equations is essential for accurately representing the conservation of mass in a chemical reaction. Each element must have the same number of atoms on both sides of the equation. This process involves adjusting coefficients in front of compounds to ensure that the total number of atoms for each element is equal, which is crucial for understanding the stoichiometry of the reaction.
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Acid-Base Reactions

Acid-base reactions involve the transfer of protons (H+) between reactants. In this context, H2XO3 acts as an acid that can donate protons to NaOH, a strong base, resulting in the formation of water and a salt. Understanding the properties of acids and bases, including their strength and how they react with each other, is vital for predicting the outcomes of such reactions.
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Stoichiometry

Stoichiometry is the quantitative relationship between reactants and products in a chemical reaction. It allows chemists to calculate the amounts of substances consumed and produced, based on balanced equations. In this scenario, stoichiometry is used to determine how much NaOH is needed to neutralize the acids formed from the reaction of XOCl2 with water, which is critical for titration calculations.
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Related Practice
Textbook Question
Alcohol levels in blood can be determined by a redox reaction with potassium dichromate according to the balanced equation What is the blood alcohol level in mass percent if 8.76 mL of 0.049 88 M K2Cr2O7 is required for complete reaction with a 10.002 g sample of blood?
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Textbook Question
Calcium levels in blood can be determined by adding oxa-late ion to precipitate calcium oxalate, CaC2O4, followed by dissolving the precipitate in aqueous acid and titrating the resulting oxalic acid (H2C2O4) with KMnO4: How many milligrams of Ca2+ are present in 10.0 mL of blood if 21.08 mL of 0.000 988 M KMnO4 solution is needed for the titration?
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Textbook Question
Assume that you have 1.00 g of a mixture of benzoic acid (Mol. wt. = 122) and gallic acid (Mol. wt. = 170)), both of which contain one acidic hydrogen that reacts with NaOH. On titrating the mixture with 0.500 M NaOH, 14.7 mL of base is needed to completely react with both acids. What mass in grams of each acid is present in the original mixture?
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Textbook Question

A compound with the formula XOCl2 reacts with water, yielding HCl and another acid H2XO3, which has two acidic hydrogens that react with NaOH. When 0.350 g of XOCl2 was added to 50.0 mL of water and the resultant solution was titrated, 96.1 mL of 0.1225 M NaOH was required to react with all the acid. (b) What are the atomic mass and identity of element X?

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Textbook Question
A procedure for determining the amount of iron in a sample is to convert the iron to Fe2+ and then titrate it with a solu-tion of Ce(NH4)2(NO3)6: What is the mass percent of iron in a sample if 1.2284 g of the sample requires 54.91 mL of 0.1018 M Ce(NH4)2(NO3)6 for complete reaction?
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Textbook Question

Some metals occur naturally in their elemental state while others occur as compounds in ores. Gold, for instance, is found as the free metal; mercury is obtained by heating mercury(II) sulfide ore in oxygen; and zinc is obtained by heating zinc(II) oxide ore with coke (carbon). Judging from their positions in the activity series, which of the metals sil-ver, platinum, and chromium would probably be obtained by (a) finding it in its elemental state?

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