Chapter 3, Problem 121
Window glass is typically made by mixing soda ash (Na2CO3), limestone (CaCO3), and silica sand (SiO2) and then heating to 1500 °C to drive off CO2 from the (Na2CO3) and CaCO3. The resultant glass consists of about 12% Na2O by mass, 13% CaO by mass, and 75% SiO2 by mass. How much of each reactant would you start with to prepare 0.35 kg of glass?
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A copper wire having a mass of 2.196 g was allowed to react with an excess of sulfur. The excess sulfur was then burned, yielding SO2 gas. The mass of the copper sulfide produced was 2.748 g. (b) What is its empirical formula?
Ammonium nitrate, a potential ingredient of terrorist bombs, can be made nonexplosive by addition of diammo-nium hydrogen phosphate, (NH4)2HPO4. Analysis of such a NH4NO3 - (NH4)2HPO4 mixture showed the mass percent of nitrogen to be 30.43%. What is the mass ratio of the two components in the mixture?
(a) Polychlorinated biphenyls (PCBs) were compounds used as coolants in transformers and capacitors, but their production was banned by the U.S. Congress in 1979 because they are highly toxic and persist in the environment. When 1.0 g of a PCB containing carbon, hydrogen, and chlorine was subjected to combustion analysis, 1.617 g of CO2. and 0.138 g of H2O were produced. What is the empirical formula?