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Ch.3 - Mass Relationships in Chemical Reactions
Chapter 3, Problem 13

Lactic acid forms in muscle tissue after strenuous exercise. Elemental analysis shows that lactic acid is 40.0% carbon, 6.71% hydrogen, and 53.3% oxygen by mass. If the molec-ular weight of lactic acid is 90.08, what is the molecular for-mula? (LO 3.11) (a) CH2O (b) C3H6O3 (c) C4H8O4 (d) C4H10O2

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Empirical Formula

The empirical formula represents the simplest whole-number ratio of the elements in a compound. To determine it, the percentage composition of each element is converted to moles, and the resulting mole ratios are simplified. In the case of lactic acid, the empirical formula can be derived from the given mass percentages of carbon, hydrogen, and oxygen.
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Molecular Weight

Molecular weight is the sum of the atomic weights of all atoms in a molecule, typically expressed in grams per mole (g/mol). It is crucial for determining the molecular formula, as the molecular formula is a whole-number multiple of the empirical formula. In this question, the molecular weight of lactic acid is given as 90.08 g/mol, which will be used to find the correct molecular formula.
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Molecular Formula Calculation

The molecular formula is derived from the empirical formula by multiplying it by a whole number that reflects how many times the empirical formula fits into the molecular weight. After determining the empirical formula from the mass percentages, the ratio of the molecular weight to the empirical formula weight is calculated to find this multiplier, allowing for the identification of the correct molecular formula for lactic acid.
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