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Ch.3 - Mass Relationships in Chemical Reactions
Chapter 3, Problem 92

An unknown liquid is composed of 5.57% H, 28.01% Cl, and 66.42% C. The molecular weight found by mass spectrometry is 126.58. What is the molecular formula of the compound?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Empirical Formula

The empirical formula represents the simplest whole-number ratio of the elements in a compound. To determine it, the percentage composition of each element is converted to moles, and the ratios are simplified. This formula provides insight into the basic composition of the compound, which is essential for further calculations.
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Molecular Weight

Molecular weight, or molar mass, is the mass of one mole of a substance, typically expressed in grams per mole (g/mol). It is determined by summing the atomic weights of all atoms in a molecule. Knowing the molecular weight allows for the conversion between mass and moles, which is crucial for identifying the molecular formula from the empirical formula.
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Weight Conversion Example

Molecular Formula

The molecular formula indicates the actual number of atoms of each element in a molecule of a compound. It can be derived from the empirical formula by multiplying the subscripts by a whole number, which is determined by the ratio of the molecular weight to the empirical formula weight. This formula provides a complete picture of the compound's composition.
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