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Ch.22 - The Main Group Elements
Chapter 22, Problem 68

Look at the properties of the alkali metals summarized in
Table 22.2, and predict reasonable values for the melting
point, boiling point, density, and atomic radius of francium.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Alkali Metals Properties

Alkali metals, found in Group 1 of the periodic table, exhibit unique properties such as low melting and boiling points, low densities, and increasing atomic radii down the group. These trends arise from their single valence electron, which influences their reactivity and physical characteristics. Understanding these properties is essential for predicting the behavior of francium, the heaviest alkali metal.
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Trends in the Periodic Table

The periodic table displays systematic trends in elemental properties, including atomic size, ionization energy, and electronegativity. For alkali metals, as you move down the group, atomic radius increases while melting and boiling points generally decrease. Recognizing these trends allows for informed predictions about francium's physical properties based on its position in the table.
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Estimation Techniques

When predicting the properties of elements like francium, estimation techniques based on extrapolation from known data of lighter alkali metals are often employed. By analyzing the trends in melting point, boiling point, density, and atomic radius of lithium, sodium, potassium, rubidium, and cesium, one can make reasonable predictions for francium, despite its rarity and radioactivity.
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