Chapter 22, Problem 144
Little is known about the chemistry of astatine (At) from direct observation, but reasonable predictions can be made.
(a) Is astatine likely to be a gas, a liquid, or a solid?
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Arrange the following oxides in order of increasing covalent character: B2O3, BeO, CO2, Li2O, N2O5.
Describe the structure of the sulfur molecules in:
b. Monoclinic sulfur
Account for each of the following observations.
b. SF4 exists, but OF4 does not.
Niobium reacts with fluorine at room temperature to give a solid binary compound that is 49.44% Nb by mass.
(c) The compound reacts with hydrogen to regenerate niobium. Write a balanced equation for the reaction.
Chlorine reacts with molten sulfur to yield disulfur dichloride, a yellowish-red liquid. Propose a structure for disulfur dichloride.