Chapter 21, Problem 26a
Locate on the periodic table the transition elements with the following electron configurations. Identify each element.
(a) [Ar] 3d74s2
(b) [Ar] 3d54s1
Video transcript
Draw the structure of all isomers of the octahedral complex [NbX2Cl4]- (X- = NCS-), and identify those that are linkage isomers.
The glycinate anion, gly-= NH2CH2CO2 -, bonds to metal ions through the N atom and one of the O atoms. Using to represent gly-, sketch the structures of the four stereoisomers of Co(gly)3.
Draw the structures of all possible diastereoisomers of an octahedral complex with the formula MA2B2C2. Which of the diastereoisomers, if any, can exist as enantiomers?
Locate on the periodic table the transition elements with the following electron configurations. Identify each element.
(c) [Kr] 4d25s2
(d) [Xe] 4f36s2
Look at the location in the periodic table of elements A, B, C, and D. What is the electron configuration of the transition metal in each of the following ions?
(c) C3+
(d) DO42-
What is the systematic name for each of the following molecules or ions? Include cis or trans prefixes for diastereoisomers. Platinum is Pt(II) in square planar complexes and Pt(IV) in octahedral complexes.
(1)
(2)
(3)
(4)