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Ch.19 - Electrochemistry
Chapter 19, Problem 82a

What reaction can occur, if any, when the following experiments are carried out under standard-state conditions? (a) Oxygen gas is bubbled through an acidic solution of Cr(NO3)3.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Redox Reactions

Redox reactions involve the transfer of electrons between species, resulting in changes in oxidation states. In the context of the question, oxygen gas can act as an oxidizing agent, potentially oxidizing chromium in Cr(NO3)3 from a lower oxidation state to a higher one, which is crucial for predicting the reaction outcome.
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Acidic Solutions

An acidic solution has a pH less than 7 and contains a higher concentration of hydrogen ions (H+). The presence of an acid can influence the solubility and reactivity of metal ions, such as chromium, and can facilitate redox reactions by providing protons that may participate in the reaction mechanism.
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Standard-State Conditions

Standard-state conditions refer to a set of specific conditions (1 atm pressure, 25°C temperature, and 1 M concentration for solutions) under which thermodynamic data is measured. Understanding these conditions is essential for predicting the feasibility and direction of chemical reactions, as they provide a baseline for comparing reaction energies and equilibria.
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