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Ch.19 - Electrochemistry
Chapter 19, Problem 128

What is meant by cathodic protection? (a) Steel is coated with a layer of paint. (b) Iron in steel is oxidized to form a protective oxide coating. (c) Steel is coated with zinc because zinc is more easily oxidized than iron. (d) A strip of magnesium is attached to steel because the magnesium is more easily oxidized than iron.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Cathodic Protection

Cathodic protection is a technique used to prevent corrosion of metal surfaces, particularly in structures like pipelines and ships. It involves making the metal surface the cathode of an electrochemical cell, which reduces the oxidation process that leads to corrosion. This can be achieved through sacrificial anodes or impressed current systems.
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Sacrificial Anodes

Sacrificial anodes are metals that are more reactive than the metal they are protecting, such as zinc or magnesium. When attached to a structure like steel, these anodes corrode preferentially, thereby protecting the steel from oxidation. This method is commonly used in marine applications and underground pipelines.
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Oxidation and Reduction

Oxidation and reduction are chemical processes that involve the transfer of electrons between substances. Oxidation refers to the loss of electrons, while reduction refers to the gain of electrons. In the context of cathodic protection, the metal being protected (like iron in steel) is reduced, preventing it from oxidizing and corroding.
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