Chapter 19, Problem 155a
The reaction of MnO4- with oxalic acid (H2C2O4) in acidic solution, yielding Mn2+ and CO2 gas, is widely used to determine the concentration of permanganate solutions. (a) Write a balanced net ionic equation for the reaction.
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Chlorine can be prepared in the laboratory by the reaction of hydrochloric acid and potassium permanganate. (a) Use data in Appendix D to write a balanced equation for the reaction. The reduction product is Mn2+.
Given the following standard reduction potentials at 25 °C, (a) balance the equation for the reaction of H2MoO4 with elemental arsenic in acidic solution to give Mo3+ and H3AsO4 and (b) calculate E° for this reaction.
The reaction of MnO4- with oxalic acid (H2C2O4) in acidic solution, yielding Mn2+ and CO2 gas, is widely used to determine the concentration of permanganate solutions. (d) A 1.200 g sample of sodium oxalate (Na2C2O4) is dissolved in dilute H2SO4 and then titrated with a KMnO4 solution. If 32.50 mL of the KMnO4 solution is required to reach the equivalence point, what is the molarity of the KMnO4 solution? .
Consider the redox titration (Section 4.13) of 120.0 mL of 0.100 M FeSO4 with 0.120 M K2Cr2O7 at 25 °C, assuming that the pH of the solution is maintained at 2.00 with a suitable buffer. The solution is in contact with a platinum electrode and constitutes one half-cell of an electrochemical cell. The other half-cell is a standard hydrogen electrode. The two half-cells are connected with a wire and a salt bridge, and the progress of the titration is monitored by measuring the cell potential with a voltmeter. (a) Write a balanced net ionic equation for the titration reaction, assuming that the products are Fe3+ and Cr3+.