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Ch.18 - Thermodynamics: Entropy, Free Energy & Equilibrium
Chapter 18, Problem 58

What is the entropy change when the volume of 1.6 g of O2 increases from 2.5 L to 3.5 L at a constant temperature of 75 °C? Assume that O2 behaves as an ideal gas.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Entropy

Entropy is a measure of the disorder or randomness in a system. In thermodynamics, it quantifies the amount of energy in a physical system that is not available to do work. An increase in volume at constant temperature typically leads to an increase in entropy, as the gas molecules have more space to occupy, resulting in greater disorder.
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Ideal Gas Law

The Ideal Gas Law is a fundamental equation in chemistry that relates the pressure, volume, temperature, and number of moles of an ideal gas. It is expressed as PV = nRT, where P is pressure, V is volume, n is the number of moles, R is the ideal gas constant, and T is temperature in Kelvin. This law allows us to predict how gases will behave under various conditions, including changes in volume.
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Change in Entropy for an Ideal Gas

The change in entropy (ΔS) for an ideal gas can be calculated using the formula ΔS = nR ln(Vf/Vi), where Vf is the final volume, Vi is the initial volume, n is the number of moles, and R is the ideal gas constant. This equation shows that entropy increases as the volume of the gas increases, reflecting the greater number of accessible microstates available to the gas molecules.
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