Ch.18 - Thermodynamics: Entropy, Free Energy & Equilibrium
All textbooksMcMurry 8th EditionCh.18 - Thermodynamics: Entropy, Free Energy & EquilibriumProblem 93
Chapter 18, Problem 93
What is meant by the standard state of a substance?
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Related Practice
Textbook Question
Consider a twofold expansion of 1 mol of an ideal gas at 25 °C in the isolated system shown in Figure 18.1. (a) What are the values of ∆H, ∆S, and ∆G for the process?
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Textbook Question
Consider a twofold expansion of 1 mol of an ideal gas at 25 °C in the isolated system shown in Figure 18.1. (b) How does this process illustrate the second law of thermodynamics?
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Textbook Question
Given the data in Problem 18.78, calculate ∆G for the vaporization of benzene at:
(a) 70 °C
Predict whether benzene will boil at each of these temperatures and 1 atm pressure.
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Textbook Question
Use the values of of ∆G°f in Appendix B to calculate the stan-dard free-energy change for the synthesis of dichloroethane from ethylene and chlorine:
C2H41g2 + Cl21g2S CH2ClCH2Cl1l2
Is it possible to synthesize dichloroethane from gaseous C2H4 and Cl2, each at 25 °C and 1 atm pressure?
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Textbook Question
Ethanol is manufactured in industry by the hydration of ethylene: Using the data in Appendix B, calculate ∆G° and show that this reaction is spontaneous at 25 °C. Why does this reaction become nonspontaneous at higher temperatures? Estimate the temperature at which the reaction becomes nonspontaneous.
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Textbook Question
Consider the conversion of 1,2-dichloroethane to vinyl chloride, the starting material for manufacturing poly(vinyl chloride) (PVC) plastics: Is this reaction spontaneous under standard-state conditions? Would it help to carry out the reaction in the presence of base to remove HCl? Explain. Is it possible to synthesize vinyl chlo-ride from graphite, gaseous H2, and gaseous Cl2 at 25 °C and 1 atm pressure?
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