Ch.18 - Thermodynamics: Entropy, Free Energy & Equilibrium
All textbooksMcMurry 8th EditionCh.18 - Thermodynamics: Entropy, Free Energy & EquilibriumProblem 71
Chapter 18, Problem 71
What are the values of x and y for the following reaction if E° = 0.91 V and ∆G° = -527 kJ?
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Textbook Question
Make a rough, qualitative plot of the standard molar entropy versus temperature for methane from 0 K to 298 K. Incorporate the following data into your plot: mp = -182 °C; bp = -164 °C; °S = 186.2 J/(K*mol) at 25 °C.
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Textbook Question
An isolated system is one that exchanges neither matter nor energy with the surroundings. What is the entropy criterion for spontaneous change in an isolated system? Give an example of a spontaneous process in an isolated system.
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Textbook Question
Give an equation that relates the entropy change in the surroundings to the enthalpy change in the system. What is the sign of ∆Ssurr for the following?
(a) An exothermic reaction
(b) An endothermic reaction
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Textbook Question
Reduction of mercury(II) oxide with zinc gives metallic mercury:
(b) Estimate at what temperature, if any, the reaction will become nonspontaneous
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Textbook Question
Elemental sulfur is formed by the reaction of zinc sulfide with oxygen:
(b) At what temperature, if any, the reaction will become nonspontaneous?
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Textbook Question
Phosphorus pentachloride forms from phosphorus trichloride and chlorine:
(a) Use data in Appendix B to calculate ∆Ssys, ∆Ssurr, and ∆Stotal for this reaction. Is the reaction spontaneous under standard-state conditions at 25 °C?
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