Ch.18 - Thermodynamics: Entropy, Free Energy & Equilibrium
All textbooksMcMurry 8th EditionCh.18 - Thermodynamics: Entropy, Free Energy & EquilibriumProblem 43
Chapter 18, Problem 43
The following reaction of A3 molecules is spontaneous.
(b) What are the signs of ∆H, ∆S, and ∆G for the reaction? Explain.Verified Solution
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Textbook Question
Which of the following processes are spontaneous, and which are nonspontaneous?
(a) Freezing of water at 2 °C
(b) Corrosion of iron metal
(c) Expansion of a gas to fill the available volume
(d) Separation of an unsaturated aqueous solution of potassium chloride into solid KCl and liquid water
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Textbook Question
Assuming that gaseous reactants and products are present at 1 atm partial pressure, which of the following reactions are spontaneous in the forward direction?
(a)
(b)
(c)
(d)
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Textbook Question
Define entropy, and give an example of a process in which the entropy of a system increases.
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Textbook Question
Predict the sign of the entropy change in the system for each of the following processes.
(a) A solid sublimes.
(b) A liquid freezes.
(c) AgI precipitates from a solution containing Ag+ and I- ions.
(d) Gaseous CO2 bubbles out of a carbonated beverage.
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Textbook Question
When rolling a pair of dice, there are two ways to get a point total of 3(1+2;2+1) but only one way to get a point total of 2(1+1). How many ways are there of getting point totals of 4 to 12? What is the most probable point total?
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Textbook Question
Consider the distribution of ideal gas molecules among three bulbs (A, B, and C) of equal volume. For each of the follow-ing states, determine the number of ways (W) that the state can be achieved, and use Boltzmann's equation to calculate the entropy of the state.
(a) 2 molecules in bulb A
(b) 2 molecules randomly distributed among bulbs A, B, and C
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