Skip to main content
Ch.18 - Thermodynamics: Entropy, Free Energy & Equilibrium

Chapter 18, Problem 9

Consider the following endothermic reaction of gaseous AB3 molecules with A2 molecules.

Identify the true statement about the spontaneity of the reaction. (a) The reaction is likely to be spontaneous at high temperatures. (b) The reaction is likely to be spontaneous at high temperatures. (c) The reaction is always spontaneous. (d) The reaction is always spontaneous.

Verified Solution
Video duration:
1m
This video solution was recommended by our tutors as helpful for the problem above.
557
views
Was this helpful?

Video transcript

Hello everyone today. We have the following problem. The gas phase decomposition of a X up, three molecules to a sub two and X up to molecules is an endo thermic reaction. The reaction is depicted in the diagram below which of the following statement is true regarding the spontaneity of the reaction. So as indicated in the question stem, this is an endo thermic reaction, which means our change in our entropy is going to be positive as we are adding energy to Are we adding heat energy into the reaction Furthermore on the reaction side, we see that we have six gas molecules, Whereas in the product side we see that we have molecules. So not only is our entropy positive, but we are increasing the disorder of our system, meaning that our entropy change is also going to be positive. The fact that we have both a positive entropy and a positive entropy means that a reaction is going to be spontaneous at high temperatures, meaning the correct answer is going to be see the reaction will be spontaneous at high temperatures and with that we've answered the question overall, I hope this helped and until next time.
Related Practice
Textbook Question
Magnesium m#etal has ΔHfusion = 9.037 kJ>mol and ΔSfusion = 9.79 J>1K mol2. What is the melting point of magnesium in °C? (LO 11.4) (a) 0.923 °C (b) 923 °C (c) 650 °C (d) 1.08 * 103 °C
489
views
Textbook Question
Identify the true statement about a spontaneous process. (a) A reaction that is nonspontaneous in the forward direction is spontaneous in the reverse direction. (b) Adding a catalyst will cause a nonspontaneous reaction to become spontaneous. (c) In a spontaneous process, the entropy of the system always decreases. (d) An endothermic reaction is always spontaneous.
579
views
Textbook Question
Calculate ∆Stotal, and determine whether the reaction is spon-taneous or nonspontaneous under standard-state conditions. (a) -429 J/K; nonspontaneous (b) -123 J/K; spontaneous (c) +3,530 J/K; nonspontaneous (d) +184 J/K; nonspontaneous
397
views
Textbook Question
Nitrogen reacts with fluorine to form nitrogen trifluoride: Calculate ∆G°, and determine whether the equilibrium composition should favor reactions or products at 25 °C (a) ∆G° = -6.7 kJ; the equilibrium composition should favor products. (b) ∆G° = -332 kJ; the equilibrium composition should favor reactants (c) ∆G° = -166 kJ; the equilibrium composition should favor products (d) ∆G° = +82.6 kJ; the equilbirum composiiton should favor reactants.
434
views
Textbook Question
Ammonium hydrogen sulfide, a stink bomb ingredient, decomposes to ammonia and hydrogen sulfide: Calculate the standard free-energy change for the rection at 25 °C if the total pressure resulting from the solid NH4S placed in an evacuated container is 0.658 atm at 25 °C. (a) -43.8 kJ (b) +1.04 kJ (c) -462 kJ (d) +5.51 kJ
463
views
Textbook Question
Consider the following graph of total free energy of reactants and products versus reaction progress for the general reaction, Reactants -> Products. At which of the four points (labeled a, b, c, and d) is Q < K?

(a) Point a (b) Point c and d (c) Point a, c, and d (d) Point b
386
views