Skip to main content
Ch.17 - Applications of Aqueous Equilibria

Chapter 17, Problem 42b

The following pictures represent solutions at various stages in the titration of a weak base B with aqueous HCl. (Cl- ions and solvent water molecules have been omitted for clarity.)

. (b) Is the pH at the equivalence point more or less than 7?

Verified Solution
Video duration:
2m
This video solution was recommended by our tutors as helpful for the problem above.
595
views
Was this helpful?

Video transcript

Hello everyone today. We have the following question. Various stages of the thai tradition of a weak base ammonia and a strong acid hydrochloric acid are depicted by the following set of four diagrams, bromine ions and water molecules have been excluded for simplicity. What is the ph of the solution at the equivalence point? So first we need to define the equivalence point and that is when the number of moles of our acid are equal to the number of moles of our base. That is the equivalence point. So in this reaction we have our ammonia harmonia reacting with our hydroponic acid to form our ammonia yum ion and our bromide ion. We know that sense hydroponic assets are strong acid, it completely dissociates into h protons and bromide ions. So this will essentially look like this if we remove the spectator ion, which in this case is bromide because it appears both in the reactant and products. We end up with this reaction here, we have our ammonia plus our hydrogen proton to give us our ammonium ion at the equivalence point, there are both are ammonium ions and our bromide ions that we omitted as a spectator ion. And since bromide is the conjugate base of a strong acid, conjugate bases of strong assets aren't necessarily basic. So we have to just focus on this ammonium ion here. This ammonium ion is a weak acid. This makes the ph at the equivalence point acidic And that is because its p will be less than seven. So the ph at these at the equivalence point. So the ph at the equivalence point Will be less than seven. And with that we have answered the question overall, I do hope this helped, and until next time.
Related Practice
Textbook Question

The following plot shows two pH titration curves, each representing the titration of 50.0 mL of 0.100 M acid with 0.100 M NaOH:

. (b) What is the approximate pH at the equivalence point for each of the acids?

967
views
Textbook Question

The following plot shows two pH titration curves, each representing the titration of 50.0 mL of 0.100 M acid with 0.100 M NaOH:

. (c) What is the approximate pKa of the weak acid?

370
views
1
rank
Textbook Question

The following pictures represent solutions at various stages in the titration of a weak base B with aqueous HCl. (Cl- ions and solvent water molecules have been omitted for clarity.)

. (a) To which of the following stages do solutions 1–4 correspond? (i) The initial solution before addition of any HCl (ii) Halfway to the equivalence point (iii) At the equivalence point (iv) Beyond the equivalence point

809
views
Textbook Question
The following pictures represent solutions at various stages in the titration of a weak diprotic acid H2A with aqueous NaOH. (Na+ ions and water molecules have been omitted for clarity.)

. (b) Which solution has the highest pH? Which has the lowest pH?
376
views
Textbook Question

The following pictures represent solutions at various stages in the titration of sulfuric acid H2A (A2- = SO4 2-) with aqueous NaOH. (Na+ ions and water molecules have been omitted for clarity.)

. (a) To which of the following stages do solutions 1–4 correspond? (i) Halfway to the first equivalence point (ii) Halfway between the first and second equivalence points (iii) At the second equivalence point (iv) Beyond the second equivalence point

1151
views
Textbook Question

The following pictures represent solutions at various stages in the titration of sulfuric acid H2A (A2- = SO4 2-) with aqueous NaOH. (Na+ ions and water molecules have been omitted for clarity.)

. (b) Which solution has the highest pH? Draw a picture that represents the solution prior to addition of any NaOH.

403
views