Chapter 14, Problem 46
The relative rates of the reaction A + B S AB in vessels (1)–(3) are 4:4:1. Red spheres represent A molecules, and blue spheres represent B molecules. (1)-(3)
(a) What is the order of the reaction in A and B?Video transcript
The following pictures represent the progress of the reaction AS B in which A molecules (red spheres) are converted to B molecules (blue spheres).
(c) Suppose that each sphere represents 6.0⨉1021 molecules and that the volume of the container is 1.0 L. What is the rate constant for the reaction in the usual units?
Consider a reaction that occurs by the following mechanism:
A + BC → AC + B
AC + D → A + CD
The potential energy profile for this reaction is as follows:
(b) Write structural formulas for all species present at reaction stages 1–5. Identify each species as a reactant, product, catalyst, intermediate, or transition state.
Consider a reaction that occurs by the following mechanism:
A + BC → AC + B
AC + D → A + CD
The potential energy profile for this reaction is as follows:
(c) Which of the two steps in the mechanism is the rate-determining step? Write the rate law for the overall reaction.
Consider a reaction that occurs by the following mechanism:
A + BC → AC + B
AC + D → A + CD
The potential energy profile for this reaction is as follows:
(d) Is the reaction endothermic or exothermic? Add labels to the diagram that show the values of the energy of reaction ΔE and the activation energy Ea for the overall reaction.