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Ch.14 - Chemical Kinetics

Chapter 14, Problem 46

The relative rates of the reaction A + B S AB in vessels (1)–(3) are 4:4:1. Red spheres represent A molecules, and blue spheres represent B molecules. (1)-(3)

(a) What is the order of the reaction in A and B?

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Hello. Everyone in this video, We're given three different vessels, vessel 12 and three. And they all have equal volumes. They all contain the reaction where X and Y yields Xy. So we can see here that the X molecules are represented by red spheres. And then the Y molecules are represented as Grace fears. And this question we're bringing asked to determine the order of direction in X and Y. So one thing that we can go ahead and assume is that the concentration is proportional to the number of molecules each vessel. So the first thing we'll do is to count each number of different molecules that we have in each vessel. So for vessel one we're gonna go ahead and count the red spheres or the X molecules first. So, we have to our X. And then we have four Y. Now for the second vessel here we have four X. And four Y. And then for vessel three we have four X. And to Y. All right. So, and vessels one and two. Let's put this in writing as well. The concentration of why remains the same. So, basically comparing vessels one and two here, that's what we're doing here. But the ex doubles. Which also means that the rate will also double before we can take away from this is that the reaction then is first order. And this is in regards to Y. R. X. So, this is whatever answers for this problem. Now, when we're comparing vessels two and 3, we can see that the concentration of X remains the same. And the concentration of why is halved, which means that the rate is also going to be had so we can take away from this, then, is that the reaction is also going to be first order in our molecule Y. So this right here, is going to be my last and final answer for this problem.
Related Practice
Textbook Question

The following pictures represent the progress of the reaction AS B in which A molecules (red spheres) are converted to B molecules (blue spheres).

(c) Suppose that each sphere represents 6.0⨉1021 molecules and that the volume of the container is 1.0 L. What is the rate constant for the reaction in the usual units?

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Textbook Question
The following pictures represent the progress of a reaction in which two A molecules combine to give a more complex molecule A2, 2 AS A2.

(b) What is the rate law?
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Textbook Question
What is the molecularity of each of the following elementary reactions? (a)

(b)

(c)

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Textbook Question

Consider a reaction that occurs by the following mechanism:

A + BC → AC + B

AC + D → A + CD

The potential energy profile for this reaction is as follows:

(b) Write structural formulas for all species present at reaction stages 1–5. Identify each species as a reactant, product, catalyst, intermediate, or transition state.

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Textbook Question

Consider a reaction that occurs by the following mechanism:

A + BC → AC + B

AC + D → A + CD

The potential energy profile for this reaction is as follows:

(c) Which of the two steps in the mechanism is the rate-determining step? Write the rate law for the overall reaction.

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Textbook Question

Consider a reaction that occurs by the following mechanism:

A + BC → AC + B

AC + D → A + CD

The potential energy profile for this reaction is as follows:

(d) Is the reaction endothermic or exothermic? Add labels to the diagram that show the values of the energy of reaction ΔE and the activation energy Ea for the overall reaction.

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