Ch.13 - Solutions & Their Properties
Chapter 13, Problem 9
A scuba diver is breathing compressed air that is 21% (by volume) oxygen at a depth of 66 ft. beneath the surface. The total pressure at this depth is 3.0 atm. The Henry's law constant (k) for O2 in water at a normal body temperature (37 °C ) is 1.93 * 10-3 mol>(L atm). What is the solubility of O2 in the blood of the diver at 66 ft. beneath the surface? (LO 13.9) (a) 1.22 * 10-3 M (b) 2.76 * 10-2 M (c) 1.22 * 10-1 M (d) 2.76 * 10-1 M
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Textbook Question
Fluoride ion is added to drinking water at low concentra- tions to prevent tooth decay. What mass of sodium fluoride (NaF) should be added to 750 L of water to make a solution
that is 1.5 ppm in fluoride ion? (LO 13.5) (a) 1.1 g (b) 2.5 g (c) 0.51 g (d) 3.1 g
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Textbook Question
A 10.0 M aqueous solution of NaOH has a density of 1.33 g/cm3 at 25 C. Calculate the mass percent of the NaOH in the solution (a) 53.2% (b) 30.1% (c) 40.0% (d) 13.3%
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Textbook Question
The molarity of a solution of sodium acetate (CH3COONa) at 20 C is 7.5 M. Use the graph showing the solubility of sodium acetate as a function of temperature to describe the solution. The solution is . (LO 13.7, 13.8) (a) Saturated (b) Unsaturated (c) Supersaturated (d) Colloidal
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Textbook Question
Which of the following solutions has the lowest vapor pres- sure? (Assume complete dissociation for ionic compounds.) (LO 13.10)
(a) An aqueous solution of 0.25 m Ca1NO322
(b) An aqueous solution of 0.30 m sodium chloride (NaCl)
(c) A mixture of 50 mL of water and 50 mL of ethanol
1CH3CH2OH2
(d) A mixture of 25 mL of water and 50 mL of ethanol
1CH3CH2OH2
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Textbook Question
12. A solution contains 4.08 g of chloroform 1CHCl32 and
9.29 g of acetone 1CH3COCH32. The vapor pressures at 35
°C of pure chloroform and pure acetone are 295 torr and 332 torr, respectively. Assuming ideal behavior, calculate the vapor pressure above the solution. (LO 13.12)
(a) 256 torr (b) 314 torr
(c) 325 torr (d) 462 torr
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Textbook Question
How many kilograms of ethylene glycol (automobile anti- freeze, C2H6O2) dissolved in 3.55 kg of water are needed to lower the freezing point of water in an automobile radiator
to - 22.0 °C? The molal freezing point depression constant for water is Kf = 1.86 1°C kg2>mol. (LO 13.13)
(a) 0.865 kg (b) 0.0420 kg
(c) 9.01 kg (d) 2.61 kg
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